. Consider the titration of the weak acid, benzoic acid, HC;H;O2. Its acid dissociation reaction is: HC>H$O2 (aq) + H:О () C:H$O? (aq) + H30* (aq) A 25.00 mL sample of a solution of benzoic acid, concentration unknown, is titrated with 0.0500M NaOH solution. A plot of the titration is shown below. 12 10 6. 4 5.0 10.0 15.0 volume of 0.0500 M NaOH ml. a) indicate where the equivalence point is, and what is the volume of base added at the equivalence point? b) what is the concentration of the benzoic acid solution (molar units)? c) what is the pKa (approximately) of benzoic acid? its K.? d) on the plot, indicate the buffering region of the titration e) from the pH at the equivalence point, estimate the pK, of benzoate ion (conjugate base to benzoic acid) [Remember, at the equivalence point, C;HO?° (aq) + H2O (1) → HC;H$O2 (aq) + OH- (aq) Hd

Introductory Chemistry For Today
8th Edition
ISBN:9781285644561
Author:Seager
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Chapter9: Acids, Bases, And Salts
Section: Chapter Questions
Problem 9.109E
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please answer only d and e in question

. Consider the titration of the weak acid, benzoic acid, HC;H;O2. Its acid dissociation reaction is:
HC>H$O2 (aq)
+ H:О ()
C:H$O? (aq) + H30* (aq)
A 25.00 mL sample of a solution of benzoic acid, concentration unknown, is titrated with 0.0500M
NaOH solution. A plot of the titration is shown below.
12
10
6.
4
5.0
10.0
15.0
volume of 0.0500 M NaOH
ml.
a) indicate where the equivalence point is, and what is the volume of base added at the equivalence
point?
b) what is the concentration of the benzoic acid solution (molar units)?
c) what is the pKa (approximately) of benzoic acid?
its K.?
d) on the plot, indicate the buffering region of the titration
e) from the pH at the equivalence point, estimate the pK, of benzoate ion (conjugate base to benzoic
acid)
[Remember, at the equivalence point, C;HO?° (aq) + H2O (1) → HC;H$O2 (aq) + OH- (aq)
Hd
Transcribed Image Text:. Consider the titration of the weak acid, benzoic acid, HC;H;O2. Its acid dissociation reaction is: HC>H$O2 (aq) + H:О () C:H$O? (aq) + H30* (aq) A 25.00 mL sample of a solution of benzoic acid, concentration unknown, is titrated with 0.0500M NaOH solution. A plot of the titration is shown below. 12 10 6. 4 5.0 10.0 15.0 volume of 0.0500 M NaOH ml. a) indicate where the equivalence point is, and what is the volume of base added at the equivalence point? b) what is the concentration of the benzoic acid solution (molar units)? c) what is the pKa (approximately) of benzoic acid? its K.? d) on the plot, indicate the buffering region of the titration e) from the pH at the equivalence point, estimate the pK, of benzoate ion (conjugate base to benzoic acid) [Remember, at the equivalence point, C;HO?° (aq) + H2O (1) → HC;H$O2 (aq) + OH- (aq) Hd
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