0: H+ CH3OH2+ H Q protonation Draw Intermediate 'H Х ■ Draw the Hemi-acetal I CH3OH deprotonation CH3OH nucleophi lic addition H3C H O H—Ö: H CH3 +
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- Curved arrows are used to illustrate the flow of electrons. Follow the arrows and draw the intermediate and product in this reaction. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. :O: H :OCH3 H OH CH3 CH3OH2+ protonation CH3OH deprotonation H3C CH3OH ОН nucleophilic addition -H Draw Intermediate Q4) Eto ₂ 5) 2-Cyclohexene-1-one O₂Et + ethylace to acetate NaOEt NaOEtAnswer choices for each are the following: unimolecular reaction Br- acetone Cl- substitution reaction elimination reaction CH3OH CH3O- F-
- The reaction below is a base-catalyzed aldol reaction. O || CH₂-C-H CH3-C-H Ethanal (Acetaldehyde) H I CH3-C-H Ethanal (Acetaldehyde) NaOH Draw curved arrows to show the movement of electrons in the step of the mechanism shown below. Arrow-pushing Instructions AC⇒x= :O: || :CH₂-C-H OH Bl CH3-CH—CH2-CH -CH₂-1-1 a 3-Hydroxybutanal (B-hydroxyaldehyde; formed as a racemic mixture) :0: :0: || CH3—CH—CH2-C-H A tetrahedral carbonyl addition intermediate XCH3 O O CH3CH₂CHCH₂CH=CHCOH HCI CH3 CHOMO CH3CH₂CHCH₂CH- CHCOH ChemDoodleⓇ CI H CH3 CH3CH₂CHCH₂CH- O CHCOH H CI this product is not observed Account for the fact that this reaction yields only a single product by drawing the carbocation intermediate leading to the observed product. Sty √n [F7 Draw the Reactant H H₂C-07 CO H-O: O CH3 CH3OH₂* protonati on 0 CH3OH2* protonation CH3OH deprotonation > H₂C I-Ö: 0: :0 CH3OH nucleophi lic addition Draw Intermediate H
- Mechanism: A reaction mechanism for the following reaction is shown below. H+ CEN CEN: N-H || -C-OH H₂O, H* Step 1 wand woled mot ozsm E Step 3 N-H C-OH C=N-H Step2 C=N-H H-O-H H₂O motno vgiene fesrigid onlt to smotnos -C=N-H a) The overall reaction is an example of b) Step 1 is c) Step 3 is d) Draw in the curved arrows for each step. e) Identify the nucleophiles and electrophiles where appropriate. f) Fill in the reaction energy diagram. H₂O: rate determining step to noipojovo hamwell sit 5(emise erit voittons 10) vanas mi sdgin al rainW di of E^ reaction progress →Which reagent is the nucleophile in the esterification reaction shown below? O || С-ОН Benzoic Acid methanol methyl benzoate benzoic acid sulfuric acid + CH₂-OH Methanol H₂SO - H₂O O || C-O-CH3 Methyl benzoateThe given reaction scheme is an example of which type of reaction? O || R₁-C-OH + R₂-OH Oxidation Fischer esterification Nucleophilic substitution Reduction Rearrangement reaction Acid O || R₁-C-O-R₂ Meeting in "General"