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- 1. For the reaction (CH3)2O + C₂H5F → [(CH3)2OC₂H5]+F¯ (a) draw the structure for the cationDraw the structures of:a. (E)-1-bromo-2-methyl-2-buteneb. (Z)-3-isopropyl-2-hepteneReagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
- 1. Draw structures for a) (2E,4Z) - hepta-2,4-diene b) (S) - 2-bromobutane21) Carbocation forms in the reaction of: A) SN1 B) SN2 С) Both D) Cannot determined1. Give balanced chemical equations for the following reactions: а. the oxidation of ethanol (two stages – use [O] in your equation but give name of the oxidising agent used in the reaction and any colour change you would see. b. the oxidation of propan-2-ol c. the dehydration of propan-2-ol d. the reaction of butylamine and hydrochloric acid (what type of reaction is this?)
- Give the major product of the following reaction. ? KMno4, "OH heat3.) HAI(CH,CH(CH3)2l2 (DIBAL-H) 1.) NBS 2.) NaCN 4.) H, H20 Thermodynamic Product Br a) 1.) b.) 1.) c.) 1.) Br Br 2) 2) 2) CN CN CN 3.) 3.) 3.) 4) 4) H. NH259. Bond Strength I. Cyclobutane II. Cyclopentane 60. Optical Rotation I. 70% R, 30% S 11.30% R, 70% S 61. Which of the following is/ are alternant aromatic compounds? A. benzene B. naphthalene C. anthracene D. all of the given choices 62. Which of the following is/ are not aromatic? A. Cyclobutadiene B. Cyclopentadiene C. Cyclohexadiene D. All of the given choices 63. The following can exhibit tautomerism EXCEPT: A. benzaldehyde B. ethanal C. Cyclohexane carbaldehyde D. Cyclohexanone 64. Which of the following substituents exhibits both - inductive effect and - Resonance effect when attached to the benzene ring? A. -OH B. -CI D. -NO2 D.-CH3 65. Alkyl groups if attached to halogen (example: tert-butyl bromide) would exhibit A. negative inductive effect B. positive inductive effect C. negative resonance effect D. positive resonance effect. 9
- Draw the organic product that is expected to form when the following compound is oxidized under biological conditions. SH oxidation reduction CH3 . You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. C. aste ba M) M)7) You want to synthesize 3-methyl-2-pentene from 2-chloro-3-methylpentane. Which reagent would you use? a. HCI, heat b. NH:(aq), 25°C c. CH:CO2NA, CH:CO2H, heat d. CH3CH2ONA, CH3CH2OH, heat e. CН:CH2ОН, heatThe following compounds have the same molecular formula as benzene. How many monobrominated products could each form? a. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.) b. How many dibrominated products could each of the compounds form if stereoisomers are included?