1. Calculate the pH of the solution after the following amounts of 0.250 M NaOH have been added to 50.0 mL of 0.200M HCI. Show all your work for each calculation (including the volumes for which the pH is given). Feel free to attach additional pages to your submission if needed. mL of NaOH pH 0.00 ANS: 0.699 36.00 39.75 40.00 40.25 44.00 66.00 ANS: 12.75

Chemistry: Principles and Practice
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter14: Chemical Equilibrium
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Titrations are acid-base reactions in which the amount of acid and base in solution are known quite precisely. The specific case where
the acid and base have been added in equivalent molar amounts, is called the equivalence point. At this point,
mol acid = mol base
%3D
At all other points in a titration, either the base is the limiting reactant (and there is excess acid) or the acid is the limiting reactant (and
there is excess base). So, except at the equivalence point, titration problems are limiting reactant problems, which means we can do
them- a lot of them!
One additional point: when there is left over strong acid (acid in excess), 100% of that excess acid is ionized to become H* ions:
[strong acid] = [H*] and pH = -log[H"]
Something similar happens for strong bases.
1. Calculate the pH of the solution after the following amounts of 0.250 M NaOH have been added to 50.0 mL of 0.200 M HCI. Show
all your work for each calculation (including the volumes for which the pH is given). Feel free to attach additional pages to your
submission if needed.
mL of NaOH
pH
0.00
ANS: 0.699
36.00
39.75
40.00
40.25
44.00
66.00
ANS: 12.75
2. The point at 40.00 mL of NaOH is a turning point in the calculations. How so? What should the pH be at/40.00 mL and why? How
about after 40.00 mL?
Transcribed Image Text:Titrations are acid-base reactions in which the amount of acid and base in solution are known quite precisely. The specific case where the acid and base have been added in equivalent molar amounts, is called the equivalence point. At this point, mol acid = mol base %3D At all other points in a titration, either the base is the limiting reactant (and there is excess acid) or the acid is the limiting reactant (and there is excess base). So, except at the equivalence point, titration problems are limiting reactant problems, which means we can do them- a lot of them! One additional point: when there is left over strong acid (acid in excess), 100% of that excess acid is ionized to become H* ions: [strong acid] = [H*] and pH = -log[H"] Something similar happens for strong bases. 1. Calculate the pH of the solution after the following amounts of 0.250 M NaOH have been added to 50.0 mL of 0.200 M HCI. Show all your work for each calculation (including the volumes for which the pH is given). Feel free to attach additional pages to your submission if needed. mL of NaOH pH 0.00 ANS: 0.699 36.00 39.75 40.00 40.25 44.00 66.00 ANS: 12.75 2. The point at 40.00 mL of NaOH is a turning point in the calculations. How so? What should the pH be at/40.00 mL and why? How about after 40.00 mL?
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