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1. Identify the acids and bases in the following reactions: (al CH3OH + H* - CH3OH;+ (b) CH3OH + NH3 - CH20- + NH3 (c) +o + ZnClz 2. Rank the following substances in order of increasing acidity: H OH CH,CCH,CCH, CHJCOH Acetone Pentane-2,4-dione Phenol Acetic acid (pK, = 19.3) (pk, = 9) (pk, = 9.9) (pk, = 4.76) 3. List the following carboxylic acids in order from strongest acid to weakest acid: CH,CH,CH,COOH K, 1.52 x 10- CH,CH,CHCOOH CICH,CH,CH,COOH K,2.96 x 10 CH,CHCH,COOH ČI K.-1.39 x 10 K.-8.9 10 4. For the following compound, a. draw its conjugate acid. h. draw its conjugate base. H;NCH;COOH 5. List the following compounds in order from strongest acid to weakest acid: CH, CH,COOH CH,OH CHCI,OH 6. Which of the following are likely to act as Lewis acids and which as Lewis bases? Which might act both ways? (a) CH3CH2OH (b) (CH3NH (d) (CHahB (e) H3C+ (e) MgBrg (n (CH3hP

1. Identify the acids and bases in the following reactions: (al CH3OH + H* - CH3OH;+ (b) CH3OH + NH3 - CH20- + NH3 (c) +o + ZnClz 2. Rank the following substances in order of increasing acidity: H OH CH,CCH,CCH, CHJCOH Acetone Pentane-2,4-dione Phenol Acetic acid (pK, = 19.3) (pk, = 9) (pk, = 9.9) (pk, = 4.76) 3. List the following carboxylic acids in order from strongest acid to weakest acid: CH,CH,CH,COOH K, 1.52 x 10- CH,CH,CHCOOH CICH,CH,CH,COOH K,2.96 x 10 CH,CHCH,COOH ČI K.-1.39 x 10 K.-8.9 10 4. For the following compound, a. draw its conjugate acid. h. draw its conjugate base. H;NCH;COOH 5. List the following compounds in order from strongest acid to weakest acid: CH, CH,COOH CH,OH CHCI,OH 6. Which of the following are likely to act as Lewis acids and which as Lewis bases? Which might act both ways? (a) CH3CH2OH (b) (CH3NH (d) (CHahB (e) H3C+ (e) MgBrg (n (CH3hP

General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter10: Acids, Bases, And Salts
Section: Chapter Questions
Problem 10.88EP: Consider the following four biological solutions: (1) bile, pH 8.0, (2) blood, pH 7.4, (3) urine, pH...
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HC H 36 46 15:11 29.0 ןו:5ר הה" HB/s Assignment 2.pdf 1. Identify the acids and bases in the following reactions: (a) CH3OH + H - CH,OH2 (b) CH3OH + NH2- - CH30- + NH3 Žnca +o (c) + ZnClz H3C HyC H 2. Rank the following substances in order of increasing acidity: H H C0H он H CH3CH. CH3CCH,CCH, CHyCOH Pentane-2,4-dione (pK, = 9) Phenol (pk, = 9.9) Acetone Acetic acid (pk,- 19.3) (pk, = 4.76) 3. List the following carboxylic acids in order from strongest acid to weakest acid: CH,CH;CH;COOH K,-1.52 x 10- CICH CH;CH;COOH K,-2.96 x 10 CH,CH;CHCOOH CH,CHCH;COOH ČI K1.39 10 K-8.9x 10 4. For the following compound, a. draw its conjugate acid. h. draw its conjugate base. H,NCH,COOH 5. List the following compounds in order from strongest acid to weakest acid: CH CH,COOH CH,OH CHCIOH 6. Which of the following are likely to act as Lewis acids and which as Lewis bases? Which might act both ways? (a) CH3CH,OH (b) (CH3)2NH (e) H3C+ (c) MgBrz (D (CHahP (d) (CH3)B III
Transcribed Image Text:HC H 36 46 15:11 29.0 ןו:5ר הה" HB/s Assignment 2.pdf 1. Identify the acids and bases in the following reactions: (a) CH3OH + H - CH,OH2 (b) CH3OH + NH2- - CH30- + NH3 Žnca +o (c) + ZnClz H3C HyC H 2. Rank the following substances in order of increasing acidity: H H C0H он H CH3CH. CH3CCH,CCH, CHyCOH Pentane-2,4-dione (pK, = 9) Phenol (pk, = 9.9) Acetone Acetic acid (pk,- 19.3) (pk, = 4.76) 3. List the following carboxylic acids in order from strongest acid to weakest acid: CH,CH;CH;COOH K,-1.52 x 10- CICH CH;CH;COOH K,-2.96 x 10 CH,CH;CHCOOH CH,CHCH;COOH ČI K1.39 10 K-8.9x 10 4. For the following compound, a. draw its conjugate acid. h. draw its conjugate base. H,NCH,COOH 5. List the following compounds in order from strongest acid to weakest acid: CH CH,COOH CH,OH CHCIOH 6. Which of the following are likely to act as Lewis acids and which as Lewis bases? Which might act both ways? (a) CH3CH,OH (b) (CH3)2NH (e) H3C+ (c) MgBrz (D (CHahP (d) (CH3)B III
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