1. Write the balanced chemical equation for the reaction of NazS2O3 and HCl in aqueous solution. 2. Consider the following experiment. Twenty mL of a 1.00 M HCl solution is added to 100 mL of a 0.100 M aqueous solution of sodium thiosulfate. After 40 seconds, the reaction has produced enough sulfur to cause a decrease in the percent transmittance to 90%T. If this reaction is repeated using 0.05 M sodium thiosulfate, how long should it take for the reaction mixture to give a 90%T reading if the reaction is first order with respect to Na2S2O3? Second order? Third order? Explain.

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1. Write the balanced chemical equation for the reaction of Na2S2O3 and HCl in aqueous solution.
2. Consider the following experiment. Twenty mL of a 1.00 M HCl solution is added to 100 mL
of a 0.100 M aqueous solution of sodium thiosulfate. After 40 seconds, the reaction has
produced enough sulfur to cause a decrease in the percent transmittance to 90%T. If this
reaction is repeated using 0.05 M sodium thiosulfate, how long should it take for the reaction
mixture to give a 90%T reading if the reaction is first order with respect to Na2S2O3? Second
order? Third order? Explain.
Transcribed Image Text:1. Write the balanced chemical equation for the reaction of Na2S2O3 and HCl in aqueous solution. 2. Consider the following experiment. Twenty mL of a 1.00 M HCl solution is added to 100 mL of a 0.100 M aqueous solution of sodium thiosulfate. After 40 seconds, the reaction has produced enough sulfur to cause a decrease in the percent transmittance to 90%T. If this reaction is repeated using 0.05 M sodium thiosulfate, how long should it take for the reaction mixture to give a 90%T reading if the reaction is first order with respect to Na2S2O3? Second order? Third order? Explain.
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