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- 7. The sedimentation and diffusion coefficients for myoglobin in dilute aqueous solution at 20°C are 2.04 x 10-13 s and 1.13 x 10-10 m²s¹, respectively. The partial specific volume of the protein is 0.741 cm3g-1, the density of the solution is 1.00 x 10-3 gcm³ and the coefficient of viscosity of the solution is 1.00 × 103 kgm 1s¹. Calculate (a) the relative molecular mass and (b) the frictional ratio of this protein. What is the probable shape of a dissolved myoglobin molecule? U nCalculate the vapor pressure of propanol (b.p. 97.0 ∘C97.0 ∘C) at the gas chromatography column temperature of 95.0 ∘C95.0 ∘C using the form of the Clausius–Clapeyron equation shown ln(?1?2)=−(Δ?vap?)(1?1−1?2)ln(P1P2)=−(ΔHvapR)(1T1−1T2) where ?R is the ideal gas constant, Δ?vapΔHvap is the enthalpy of vaporization, ?1T1 and ?2T2 are two different temperatures, and ?1P1 and ?2P2 are the vapor pressures at the respective temperatures. The enthalpy of vaporization can be estimated using Trouton's rule, Δ?∘vap=(88 J·mol−1⋅K−1)×?bp.ΔHvap∘=(88 J·mol−1⋅K−1)×Tbp. ?=P= TorrTorr Calculate the vapor pressure of pentane (b.p. 36.0 ∘C36.0 ∘C) at the same column temperature. ?=P= TorrTorr For compounds of the same chemical class, what is the relationship between vapor pressure of a compound and retention in gas chromatography? As the vapor pressure decreases, retention time decreases. As the vapor pressure increases, retention time increases. As…1. Assume that the hydrocarbonlike interior cavity of the SDS micelle has a diameter of - 3 nm and that it contains three solubilized benzene molecules. Calculate the "local" concentration of benzene in the micelle 2. Assuming that at 298 K the CMC for a cerrain surfactant is 6 X 10-3 M and that its mean aggregation number is 70, estimate the concentration of micelles if the bulk sur factant concentration is 0.08 M. 3. A quantity (390 mg) of n-hexane is solubilized in 100 mL of the surfactant solution in question 2. Assuming that all the solubilized n-hexane molecules are in the micelles, what is the mean occupation number of 71-hexane in the micelles? 4. For the system in question 2, estimate tlGo for micellization if the molecular weight of the surfactant is 326 g mol-I . If the enthalpy of micellization is 8 kJ mol- I, find the en tropy change when 1 mol of micelles forms from 70;:mhnomers. I ONLY NEED THE SOLUTION FOR QUESTION 4. thank you!
- units of slope: m = M-! Report the y-intercept, b, of the plot and its units. units of y-intercept: b = * TOOLS unitless y x10 Use the plot to determine the molar absorptivity, e, of molecule X at this wavelength and its units. units of molar absorptivity: € =Caffeine Benzoic acid y = 66.391x R2E0.9995 y= 23.633x R? =0:9999 0.5 Injection Volume Injection Volume Aspartame Saccrine y = 6.2204x.. R2 =0.9997 y = 21.43x R² = 0.9891 2.5 0.5 2.5 Injection Volume Injection Volume (Abs) Peak height (Abs) Peak height 2. (Abs) Peak height (Abs) Peak heightA certain saturated salution of Cas(POrlz has [Cat]= PO48 ] = 2.9 X 107 What is the value of Kps for Caz (PO4)z? %3D
- The sedimentation coefficient for a protein in solution is determined to be 4.3 S, and the diffusion coefficient to be 5.5x10-11 m2s-1 (vb = 0.74 mLg-1; density = 1.0 gmL-1; and viscosity = 1.0x10-3 Pas-1). Use this information to calculate the molar mass (kgmol-1) of the protein. Assume temperature of 298 K.40. Which of the following affects the sedimentation of a particle in gradient ultracentrifugation? Group of answer choices the affinity of the particle for the gradient solution the viscosity of the particle solution the total mass of the gradient and tube the density of the gradient solution the number of hydrophobic residuesChemistry Question
- The homogeneity of the chloride level in a water sample from a lake was tested by analyzing por- tions drawn from the top and from near the bottom of the lake, with the following results in ppm CI: Top 26.30 Bottom 26.22 26.43 26.32 26.28 26.20 26.19 26.11 26.49 26.42 (a) Apply the i test at the 95% confidence level to determine if the means are different. (b) Now use the paired / test and determine whether there is a significant difference between the top and bottom values at the 95% confidence level. (c) Why is a different conclusion drawn from using the paired i test than from just pooling the data and using the normal i test for differences in means?Osmotic pressure of the gold sol withconcentration of 4 g/l at 293 K is 8 Pa.Calculate the particles diffusion coefficient if gold density is 19.3 g/cm3, medium viscosity 10-3 Pa•s.Substances A and B with capacity factors 6.3 and 11.4, respectively, are being carried by a mobile phaseflowing at a velocity of 0.53 mm/s. What is the length of a column required to separate these two substanceswith a resolution of 1? Assume that the sample zones for both A and B broaden based on the van Deemter equation H = 0.35 + 0.48/u+ 0.57u where Hand u are expressed in µm and mm/s, respectively.