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- For the reaction k1 k2 [Cr(H2O)4Cl2]+(aq) ====è [Cr(H2O)5Cl]2+ =====è [Cr(H2O)6]3+(aq) k1 = 1.78 x10-3/s and k2 = 5.8 x10-5/s for [Cr(H2O)Cl2]+ = 0.0174 mol/L at 0oC a.) Calculate the concentration of species at t =500sec. b.) Calculate the value of t at which the value of [Cr(H2O)5Cl]2+ is a maximum. c.) What is the maximum value of [Cr(H2O)Cl]2+8) Bipyridine ligands are known to be redox active. Draw the product of the hypothetical reduction of the following molecule where you assume the bpy is getting reduced and not the metal. Draw a static resonance structure showing the positions of any multiple bonds. What might you look for in the solid- state crystal structure (or even a calculated structure) to determine if a bpy is exhibiting redox-active behavior 120 2e0When dimethoxyethane reacts with I+, it forms a Lewis acid-base complex in which both oxygens bond to the iodine. What is the electron group geometry (from VSEPR theory) of the complex? Make a good Lewis drawing of the Lewis complex, using dash-wedge notation and correctly showing formal charges and the location of the lone pairs.
- In spite of the high equilibrium constant (K = 1025) for the reaction given here, the reaction proceeds very slowly, reaching equilibrium only after several days at room temperature. [Co(NH3)6]3+ + 6 H3O* = [Co(H20)6]3+ + 6 NH,* The observation is consistent with: the activation energy for the forward reaction being low. [Co(NH3)6]3+ being unstable in strong acid. [Co(NH3)6]3+ being more labile than [Co(H2O)6]3+. the classification of [Co(NH3)6]3+ as an inert complex.1. Write the oxidation and reduction half equations of this reaction. Co(NO3)2.6H2O + 4NH3(aq) + (NH4)2CO3 + ½ H2O2 → [Co(NH3)4CO3]NO3 + NH4NO3 + 6H2O + NH4OH 2. Ali synthesized an octahedral complex with the formula, [Co(NH3)4CO3]Cl. - Draw the structure of this complex. Name it.CI Ph. Ph Me PPH3 -P'Pr2 P'Pr2 Са ト… Re Ph2 PPH3 X = CI Can someone help me find 1) the formal oxidation state of the metal in each structure, 2) total electron count in each complex, and 3) d-electron count for the metal in each complex?
- 09:10 4G What is the geometry for the [Cr(H20)4C12] compound OA Square planar OR Tetrahedral OC Trigonal planar ODOctahedral Add a caption... > Status (Custom)t2g In the octahedral field, dx2-v2 and d,2 are denoted as e, orbitals with the s-symmetry while dyy, dyz, and dyz are denoted as XZ orbitals with the p-symmetry. In which of the following complexes, are t2, orbitals considered non-bonding orbitals? [C:Clgj³- O ICr(CN),1*- O [Cr(OH2)6]³+ O [Cr(NH3)g]3+True or False: Elements exists in various oxidation states in the second and third transition series due to the availability of various electrons in the 3d and 6s subshells. D-block elements could react with the orbitals of the neighboring ligands because of the existence of vacant and low energy orbitals All halogens have very pungent odors and can cause inflammation of the mucous membranes.
- Chemistry 2. Predict the transition metal-containing products of the following reactions and label which type of organometallic reaction occurred. a. [Mn(CO)s] + H₂C=CH-CH₂Cl → b. trans-Ir(CO)CI(PPH3)2 + CH₂ → c. (n-C3Hs)Fe(CO)(CH3)+PPhy > d. H₂C-Mn(CO)s + SO₂ → e. W(CO) + CeHsLi → f. Fe(CO)s + NaCsHs →8a. Name and draw the appropriate geometric isomers for Pt(NH3)4Cl2[Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O Explain why the addition of water changes the equilibrium position even though the concentration of water is essentially constant and normally not included in the equilibrium constant expression. What are two functions that water performs in this reaction?