1/2 |--2-/ (15) ² obc 2лс (5.34) For diatomic molecules, these lines occur at around 10³ cm, which is in the infrared region. Equation 5.34 enables us to determine force constants if the fundamental vibrational frequency is known. For example, for HCl, is 2.886 × 10³ cm and so, according to Equation 5.34, the force constant of H³5Cl is obs

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 64AP
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(4)
2TC μ
1/2
(5.34)
For diatomic molecules, these lines occur at around 10³ cm, which is in the infrared
region. Equation 5.34 enables us to determine force constants if the fundamental
vibrational frequency is known. For example, for HCl, is 2.886 × 10³ cm and
so, according to Equation 5.34, the force constant of H³5Cl is
obs
Transcribed Image Text:1 (4) 2TC μ 1/2 (5.34) For diatomic molecules, these lines occur at around 10³ cm, which is in the infrared region. Equation 5.34 enables us to determine force constants if the fundamental vibrational frequency is known. For example, for HCl, is 2.886 × 10³ cm and so, according to Equation 5.34, the force constant of H³5Cl is obs
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