1)Use the nature of the bonding in d-transition metal complexes with CO to explain why HCo(CO)4 and HV(CO)6 are strong acids in water . 2)Why did the observed chemistry of thallium mislead Mendelev to place the group 13 element (Tl) in a group with Li ,Na, K ,Rb ,and Cs ?

1)Use the nature of the bonding in d-transition metal complexes with CO to explain why HCo(CO)4 and HV(CO)6 are strong acids in water . 2)Why did the observed chemistry of thallium mislead Mendelev to place the group 13 element (Tl) in a group with Li ,Na, K ,Rb ,and Cs ?

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter19: Transitition Metals, Coordination Chemistry And Metallurgy

Section: Chapter Questions

Problem 19.4QE

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Question

1)Use the nature of the bonding in d-transition metal complexes with CO to explain why HCo(CO)₄and HV(CO)₆are strong acids in water .

2)Why did the observed chemistry of thallium mislead Mendelev to place the group 13 element (Tl) in a group with Li ,Na, K ,Rb ,and Cs ?

Definition Definition Elements containing partially filled d-subshell in their ground state configuration. Elements in the d-block of the periodic table receive the last or valence electron in the d-orbital. The groups from IIIB to VIIIB and IB to IIB comprise the d-block elements.

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