2. A combined system is formed from two separate systems of N localized atoms of spin-1/2 each. While the two systems remain separate (a) Find the number of configurations which give a total spin excess S = S, +S, %3D where S, and S, are the excess spins of the separate systems. (b) For what values of S, and S, is this number of configurations maximum?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 56AP
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A combined system is formed from two separate systems of N localized atoms of spin-1/2 each.
While the two systems remain separate
(a) Find the number of configurations which give a total spin excess S = S, +S,
where S, and S, are the excess spins of the separate systems.
(b) For what values of S, and S, is this number of configurations maximum?
Transcribed Image Text:2. A combined system is formed from two separate systems of N localized atoms of spin-1/2 each. While the two systems remain separate (a) Find the number of configurations which give a total spin excess S = S, +S, where S, and S, are the excess spins of the separate systems. (b) For what values of S, and S, is this number of configurations maximum?
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