3-3. Piché and Larachi (2007) proposed the following reaction for the oxidation of polysulfide ions (S,2 where n can be any value >2) to form thiosulfate ions (S2O32-) and colloidal sulfur (Sg): 3 2- S8 S,2-+02 S2O32+ 8 (a) For n=6, write expressions for rs,0,2- and rs, in terms of rs2-, if all the rates are given in units of %3D mol/L h. (b) Repeat part a, if the rates are in mg/L-h of the respective chemicals; designate these rates as r. (c) Repeat part a, if the rates are in mg S/L h; designate these rates as r".

Fundamentals Of Analytical Chemistry
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Chapter7: Statistical Data Treatment And Evaluation
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Problem 7.26QAP
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3-3. Piché and Larachi (2007) proposed the following
reaction for the oxidation of polysulfide ions (S,2
where n can be any value >2) to form thiosulfate ions
(S2O32-) and colloidal sulfur (Sg):
3
S8
S2-+02 S2O32 +
8
(a) Forn 6, write expressions for rs,0,2- and rse in
terms of rs2-, if all the rates are given in units of
mol/L h.
(b) Repeat part a, if the rates are in mg/L-h of the
respective chemicals; designate these rates as r'.
(c) Repeat part a, if the rates are in mg S/L h;
designate these rates as r".
Transcribed Image Text:3-3. Piché and Larachi (2007) proposed the following reaction for the oxidation of polysulfide ions (S,2 where n can be any value >2) to form thiosulfate ions (S2O32-) and colloidal sulfur (Sg): 3 S8 S2-+02 S2O32 + 8 (a) Forn 6, write expressions for rs,0,2- and rse in terms of rs2-, if all the rates are given in units of mol/L h. (b) Repeat part a, if the rates are in mg/L-h of the respective chemicals; designate these rates as r'. (c) Repeat part a, if the rates are in mg S/L h; designate these rates as r".
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