4 NH3(g) +5 O2(g) = 4 NO(g) + 6 H,O(g) AH =-904.4 kJ Consider the equilibrium system represented in the reaction above. Will the concentration of NO ncrease, decrease, or remain the same when the following experimental changes are made: a. NH, is added d. The volume of the container is reduced b. [H,O] is increased e. A catalyst is added c. O, is removed f. The temperature is increased

4 NH3(g) +5 O2(g) = 4 NO(g) + 6 H,O(g) AH =-904.4 kJ Consider the equilibrium system represented in the reaction above. Will the concentration of NO ncrease, decrease, or remain the same when the following experimental changes are made: a. NH, is added d. The volume of the container is reduced b. [H,O] is increased e. A catalyst is added c. O, is removed f. The temperature is increased

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter17: Equilibrium

Section: Chapter Questions

Problem 12CR

See similar textbooks

Similar questions

A 100.-gram sample of sodium chloride (NaCl) is added to 100. mL of water at 0 C. After equilibrium is reached, about 64 g of solid remains undissolved. Describe the equilibrium that exists in this system at the particulate level.
The following equilibrium is established in a closed container: C(s)+O2(g)CO2(g)H=393kJmol1 How does the equilibrium shift in response to each of the following stresses? (a) The quantity of solid carbon is increased. (b) A small quantity of water is added, and CO2 dissolves in it. (c) The system is cooled. (d) The volume of the container is increased.
. Ammonia. a very important industrial chemical. is produced by the direct combination of the following elements under carefully controlled conditions: N2(g)+3H2(g)2NH3(g)Suppose. in an experiment, that the reaction mixture is analyzed after equilibrium is reached, and it is found, at a particular temperature. that [NH3]=0.25M,[H2]=3.4103M, and [N2]=5.3105M. Calculate the value of K at this temperature.
. Explain why the development of a vapor pressure above a liquid in a closed container represents an equilibrium. What are the opposing processes? How do we recognize when the system has reached a state of equilibrium?
Colorless N2O4 gas decomposes to form red-brown colored NO2 gas. Describe how the concentrations of N2O4 and NO2 would change increase or decrease as equilibrium was established in a sealed container that initially contained only N2O4. What observation would indicate that equilibrium had been established?
Benzaldehyde, a flavoring agent, is obtained by the dehydrogenation of benzyl alcohol. C6H5CH2OH(g)C6H5CHO(g)+H2(g)K for the reaction at 250C is 0.56. If 1.50 g of benzyl alcohol is placed in a 2.0-L flask and heated to 250C, (a) what is the partial pressure of the benzaldehyde when equilibrium is established? (b) how many grams of benzyl alcohol remain at equilibrium?
A piece of gold (10.0 g, CAu = 0.129 J/g K) is heated to 100.0 C. A piece of copper (also 10.0 g, CCu = 0.385 J/g K) is chilled in an ice bath to 0 C. Both pieces of metal are placed in a beaker containing 150. g H2O at 20 C. Will the temperature of the water be greater than or less than 20 C when thermal equilibrium is reached? Calculate the final temperature.
Consider an equilibrium mixture of four chemicals (A. B. C. and D. all gases) reacting in a closed flask according to the following equation: A+BC+Da. You add more A to the flask. How does the concentration of each chemical compare to its original concentration after equilibrium is re-established? Justify your answer. h. You have the original set-up at equilibrium, and add more D to the flask. How does the concentration of each chemical compare to its original concentration after equilibrium is re-established? Justify your answer.
A 1.00-L vessel at 400 C contains the following equilibrium concentrations: N2, 1.00 M; H2, 0.50 M; and NH3, 0.25 M. How many moles of hydrogen must be removed from the vessel to increase the concentration of nitrogen to 1.1 M?
Consider the following equilibrium: COBr2(g) CO(g) + Br2(g)Kc = 0.190 at 73 C (a) A 0.50 mol sample of COBr2 is transferred to a 9.50-L flask and heated until equilibrium is attained. Calculate the equilibrium concentrations of each species. (b) The volume of the container is decreased to 4.5 L and the system allowed to return to equilibrium. Calculate the new equilibrium concentrations. (Hint: The calculation will be easier if you view this as a new problem with 0.5 mol of COBr2 transferred to a 4.5-L flask.) (c) What is the effect of decreasing the container volume from 9.50 L to 4.50 L?
A mixture of N2, H2, and NH3 is at equilibrium [according to the equationN2(g)+3H2(g)2NH3(g)] as depicted below: The volume is suddenly decreased (by increasing the external pressure) and a new equilibrium is established as depicted below: a. If the volume of the final equilibrium mixture is 1.00 L, determine the value of the equilibrium constant, K. for the reaction. Assume temperature is constant. b. Determine the volume of the initial equilibrium mixture assuming a final equilibrium volume of 1.00 L and assuming a constant temperature.
For the system PCl5(g)PCl3(g)+Cl2(g)K is 26 at 300C. In a 1.0-L flask at 300C, a gaseous mixture consists of all three gases with the following partial pressures: PPCl5=0.026atm,PPCl3=0.65atmPPCl2=0.33atm (a) Is the system at equilibrium? Explain. (b) If the system is not at equilibrium, in which direction will the system move to reach equilibrium?