4. Formic acid, HFor, has a K, value equal to about 1.8 × 10¬4. A student is asked to prepare a buffer having a pH of 3.55 from a solution of formic acid and a solution of sodium formate having the same molarity. How many milliliters of the NaFor solution should she add to 20. mL of the HFor solution to make the buffer? (See discussion of buffers.) pHa pka +10g ( conjugate base) (aud) 3.55= 3.744 + log (0.02 -4 ka =18x10 pH= 355 Pkq= -log ka = -log ( 1.0 x104) 0.6397= = 3,744 V= 0.0312 L V= 31.2 mL 31.2 mL How many mL of 0.10 M NAOH should the student add to 20 mL 0.10 M HFO if she wished to prepare a buffer with a pH of 3.55, the same as in Problem 4?

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Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.149QP: A solution of weak base is titrated to the equivalence point with a strong acid. Which one of the...
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4. Formic acid, HFor, has a K, value equal to about 1.8 × 10-4. A student is asked to prepare a buffer having
a pH of 3.55 from a solution of formic acid and a solution of sodium formate having the same molarity.
How many milliliters of the NaFor solution should she add to 20. mL of the HFO solution to make the
buffer? (See discussion of buffers.)
-4
ka =18x10
pH= 355
pHs pka +1og ( conjugate base)
(aud)
3.55= 3.744 + log ()
Pka= -logka
= -log ( 1.0x104)
=D 3.744
0.6397=/0.02
V= 0.0312 L
V: 31.2 mL
31.2
mL
5. How many mL of 0.10 M NAOH should the student add to 20 mL 0.10 M HFor if she wished to prepare a
buffer with a pH of 3.55, the same as in Problem 4?
Ka=
mL
Transcribed Image Text:4. Formic acid, HFor, has a K, value equal to about 1.8 × 10-4. A student is asked to prepare a buffer having a pH of 3.55 from a solution of formic acid and a solution of sodium formate having the same molarity. How many milliliters of the NaFor solution should she add to 20. mL of the HFO solution to make the buffer? (See discussion of buffers.) -4 ka =18x10 pH= 355 pHs pka +1og ( conjugate base) (aud) 3.55= 3.744 + log () Pka= -logka = -log ( 1.0x104) =D 3.744 0.6397=/0.02 V= 0.0312 L V: 31.2 mL 31.2 mL 5. How many mL of 0.10 M NAOH should the student add to 20 mL 0.10 M HFor if she wished to prepare a buffer with a pH of 3.55, the same as in Problem 4? Ka= mL
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