43. Identify the reagent that will produce the following brominated product in greatest amount.BrA. Br₂/uv?B. Br₂/FeBr3C. NBSD. Br2/CC1444. Under acidic condition, which of the following compounds can not be oxidized by KMnO4.A. toluene B. 2-butene C. methylcyclohexane D. 2-butyne 40. Which of the following is the major organic product of the reaction sequence below?H₂OH₂SO4HgSO4A.B.C.D.HO₂S--C=C-HOHol+ CH3COHCH₁₂0HC=C-H41. All of the following statements are limitations to the Friedel-Craft alkylation EXCEPTA. Highly deactivated aromatic rings are unreactive under Friedel-Crafts conditions.B. Carbocation rearrangement can occur during alkylation reaction.C. Over-alkylation of the ring is a distinct possibility.D. Aniline derivatives are so reactive that over-alkylation is a possibility.

since you posted a question with multiple subparts, we will solve the first three subparts for you.…

Answered: 43. Identify the reagent that will…

43. Identify the reagent that will produce the following brominated product in greatest amount. Br A. Br₂/uv ? B. Br₂/FeBr3 C. NBS D. Br₂/CC14

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: The electromagnetic spectrum of an analytical sample showed absorption at 3200 cm^-1. calculate the…

Q: 7.4 Assign the alkene stereochemistry as E or Z D (a) E (b) Z -OH OH

Q: 1. What is an enzyme? 2. What is the function of an enzyme? 3. Which graph would represent enzyme…

A: This chapter is from Biochemistry. As per Bartleby guideline I can provide answers for first 3…

Q: In the following net ionic equation, identify each reactant as either a Bronsted-Lowry acid or a…

Q: Use the following data to determine the average of %K3[Al(C₂O4)3] in samples prepared by students.…

A: According to the question, we can write the balanced chemical equation between KMnO4 and…

Q: This energy diagram shows the allowed energy levels of an electron in a certain atom or molecule: A…

A: Lowest energy state is called the ground state. States higher in energy than the ground state are…

Q: QUESTION 42 What is the molarity of MgCl 2 in 325 mL of solution that contains 15.6g MgCl 2?…

Q: Why is it in Cm3 and not mL?

A: The answer of the given question is explained below:

Q: What is the total binding energy of 12 C? 2C atomic mass = 12.000 amu; mass of proton = 1.007825…

Q: Calculate AH°298, AS 298, and AG 298 for the combustion of 1 mole of nonane, C9H₂0 (MW 128.2 g/mol).…

A: Although in question nonane is asked, but the data provided for octane.

Q: From the following systems (i.e.. pair of metals): Ni-Al. Co-Zn, and Fe-Cr. Element Ni C H 0 C.…

A: Given metal pair : Ni-Al Co-Zn Fe-Cr

Q: A hot air balloon is filled with 635 L of Helium at 22 °C and pressure of 0.934 atm. What is the…

A: Given - Volume= 635 L = V1= V2 T1=22°C = 22 + 273 = 295 K T2=155°C = 155 + 273 = 428 K P1=0.934atm…

Q: Kw(293 K) = 0.67 × 10-14 M² Kw(298 K) = 1.00 × 10-14 M² Kw(303 K) = 1.45 × 10-14 M² Assuming that…

Q: CI Br 4

A: The given problem is based on the nomenclature of organic compounds.

Q: Ammonia gas can be prepared by the reaction CaO(s) + 2NH₂Cl(s)2NH₂(g) + H₂O(g) +CaCl, (s) In an…

A: Given, the mass of NH3 formed in the experiment = 27.5 g The predicted mass of NH3 that should be…

Q: b) c) H₂C. OH NH CH₂ CH₂ CH3 2 methoxy, 5 Nitro benzoic and Isopropyl but-3-ynoate CH3 OH N methyl,…

Q: Liquid X is known to have a lower vapor pressure and lower surface tension than Liquid Y. Use these…

A: The relationship between boiling point and vapour pressure is inverse. Because it takes more…

Q: 13 11 9 7 5 3 1 0 Titration of 10.0mL of an unknown diprotic acid with 1.00M NaOH. 5 pH = 4.01 15…

A: Observe the graph

Q: Complete by circling the correct choice Enzymes are most active at an optimum temperature (usually…

A: To circle the correct statement about the enzymes. "Since you have asked multiple questions, we…

Q: 25. Identify the major product and the mechanism of the reaction below. t HBr ROOR

A: Note : Since you have posted multiple questions, we are entitled to answer the first only. Please…

Q: A sample of bromine has a mass of 40.8 grams. a. How many Br atoms are there in the sample? atoms b.…

Q: 1- Prepare 0.010 M sodium thiosulphate in 250.0-ml vol.flask. 2- Prepare 0.40 M sodium acetate in…

Q: OO HUAWEI P30 LEICA TRIPLE CAMERA a N M

A: Titration: Titration is a quantitative technique usually performed to determine the unknown…

Q: 4. A solution contains only these ions: mercury (I), lead (II), copper (II), bismuth (III), nickel…

A: Cation separate

Q: Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction entropy…

Q: Commercially, potatoes can be peeled by treatment with NaOH which helps loosen the skins which are…

Q: Using the reaction above, show and explain on video how many liters of hydrogen can be created if I…

Q: How to calculate volume of concentrated solution needed to prepare a diluted solution 1) How many…

Q: The element oxygen was prepared by Joseph Priestley in 1774 by heating mercury(II) oxide: HgO(s) →…

Q: Select the correct proper or common name for the compound. CI HO The compound is named: O…

Q: Propose mechanisms and products for the following transformations. Use the curved-arrow formalism to…

A: For this given reaction now we have to find out the mechanistic pathway as follows

Q: 1. Free radicals are generated by subjecting a molecule such as chlorine or bromine gas to A. high…

Q: CI + CH3OH methanol Suppose you were told that the above reaction was a substitution reaction but…

A: For the given substitution reaction, the outcome of the compound is heavily dependent on the nature…

Q: 5. Which type of spectroscopy (IR, ¹H NMR, 13C NMR) would be good to distinguish between…

Q: A piece of iron (specific heat, 0.444 J/g•°C) is added to 168 grams of water (specific heat, 4.184…

Q: Question 6: Designate the R/S configuration for any chiral centers in the following molecules 1. 3.…

Q: Imagine an alternate universe where the value of the Planck constant is 6.62607 x 10 J.s. In that…

Q: A gas that has a volume of 8.5 liters, a temperature of 35 0C, and an unknown pressure has its…

Q: Find the pH of 0.1 M of the different form of histidine species. (See image attached) b) What is…

A: Histidine is an amino acid

Q: Hydrogen gas can be produced in the laboratory through the reaction of magnesium metal with…

A: Given: Mass of Mg = 30.0 g Pressure of H2 = 780 mmHg Temperature = 26oC Molar mass of Mg = 24 g/mol

Q: A chemist titrates 100.0 mL of a 0.8693 M aniline (C,H, NH₂) solution with 0.4894 M HCl solution at…

Q: CREATE A CONCEPT MAP FROM THIS PASSAGE: In this article, we will discuss polyatomic ions. The prefix…

A: 1) In polyatomic ions prefix Poly means many while in monoatomic ions mono means one. 2) Polyatomic…

Q: What is the pH of solution when 19.7 mL of strong base having molarity 0.00269 M is mixed with an…

Q: Be sure to answer all parts. According to advertisements, "a diamond is forever". Calculate AH°,…

A: Given -> Diamond ----> graphite

Q: Draw the arrow pushing mechanism of the following reaction

Q: Sodium sulfate is slowly added to a solution containing 0.0500 M Ca²+ (aq) and 0.0250 M Ag* (aq).…

Q: 2. Calculate the degree of sp-hybridization for a C atom in the following molecules/materials: a)…

Q: What is AG for the reaction of iron (II) ions with one mole of permanganate ions? (F= 96,500 C mol…

Q: Consider the nitrogen atoms (labeled A-D) in the molecule of 8-Chlorotheophyline shown below. Which…

A: we have to determine the nitrogen atoms which do not have delocalized electrons

Q: For the reaction 2H₂O(1) 2H₂(g) + O₂(g) AH = 572 kJ and AS° = 327 J/K At standard conditions, this…

Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

43. Identify the reagent that will produce the following brominated product in greatest amount.
Br
A. Br₂/uv
?
B. Br₂/FeBr3
C. NBS
D. Br2/CC14
44. Under acidic condition, which of the following compounds can not be oxidized by KMnO4.
A. toluene B. 2-butene C. methylcyclohexane D. 2-butyne

40. Which of the following is the major organic product of the reaction sequence below?
H₂O
H₂SO4
HgSO4
A.
B.
C.
D.
HO₂S-
-C=C-H
OH
ol
+ CH3COH
CH₁₂
0
H
C=C-H
41. All of the following statements are limitations to the Friedel-Craft alkylation EXCEPT
A. Highly deactivated aromatic rings are unreactive under Friedel-Crafts conditions.
B. Carbocation rearrangement can occur during alkylation reaction.
C. Over-alkylation of the ring is a distinct possibility.
D. Aniline derivatives are so reactive that over-alkylation is a possibility.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Provide the reagents. Но + enantiomer A 1. KOt-Bu, heat 2. mCPBA 3. MeMgBr 4. H2O B. 1. conc. H,SO4, heat 2. MCPBA 3. MeBr С. 1. РBгз 2. KOt-Bu 3. mCPBA 4. MeMgBr 5. H2O D. 1. Br2, hv 2. KOt-Bu 3. mCPBA 4. MeMgBr 5. H2O E. 1. Br2, hv 2. KOt-Bu 3. MCPBA 4. MeBr 5. H2O F. 1. Br2, FeBr3 2. KOt-Bu 3. mCPBA 4. MeMgBr 5. H2O G. 1. Br2, FeBr3 2. KOt-Bu 3. mCPBA 4. MeBr 5. H20
7. Provide structures for the major organic products of each of the following reactions. Be careful to indicate product stereochemistry when necessary. a. b. C. d. OH OH Br OH OH PBr₂ Savail slupplom xiris low afat HBr (excess) CH₂CH₂MgBr, dhe ether HI w abon wuthwold a
2. Which one of the following is the electrophile in the Friedel-Crafts acylation reaction? A. NO2 B. CH,CO C. AICI, 4. SO, 3. The major product in the following reaction is CH₂ OH CH₂ A OH NO₂ O₂N HNO3/H₂SO4 B CH₂ OH SO₂H C CH₂ OH NO₂ CH3 D OH NO₂ SO₂H
Which of the following statements regarding Friedel-Crafts reaction is wrong? Oa. Friedel-Crafts Alkylation is often difficult to stop after single substitution. O b. Acylation of substituted benzene with electron withdrawing group proceeds much faster than that with elect C. Alkylation and Acylation of benzene are Friedel-Crafts reactions. O d. One of Friedel-Crafts alkylation limitation is a skeletal rearrangement of the carbocation sometimes occurs.
Synthesize the following molecules from cyclohexanol and any other organic/inorganic reagents. a. CO2H b. CH2CH2CH3 с.
Provide the reagents necessary to carry out the following conversion. ABCDE A. B. C. PCC/CH2Cl2 Br2, CCl4 E. None of these D. OH KMnO4/NaOH/H₂O Na2Cr2O7/H2SO4/H2O H
2. Predict the major organic product(s) for each of the following reactions. Be sure to clearly indicate the proper stereochemical relationships between groups (if appropriate), and write the word "racemic" next to any compound that is formed as a racemic mixture. a. b. C. d. e. f. H3C H 2) H3O+ NaCN aq. NaOH NH NaOH H₂O, A CN 1) LiAlH4 2) H₂O HO CN H3O A g. Hic i CH₂ H3C NaCN aq. NH4Cl H3C. NH2 SOCI2 pyridine h. CN 1) PhMgBr H3C CH3 2) H3O+ i. H3C CN NaOH Ph CH3 H₂O j. 1) LiAlH4 N' Ph H 2) H₂O k. CN H3C H3O CH3 A I. OH 1) LiAlH4 Ph CN 2) H₂O m. H3C CN 1) i-Bu₂AIH CH3 Ph 2) H3O+ n. NH2 1) H3OA H3C CN 2) neutralize
4. Reactivity. Propose a mechanism for each of the following transformations to explain the observed regioselectivity and stereochemistry. a. -COCI SiMe3 AICI3 Mé `Me 76% b. Me (Ph;P)4Pd (cat.) CO-Me EtzN, CH3CN, reflux Me MeO2C 80% с. Me Me SiMe3 n-BugNF DMF, HMPA 69% d. EtAICI (2 eq) toluene -SiMe3 85%
3. Provide mechanisms for the following reactions. a. OH b. H2180 180H cat. H 180 H₂O cat. H* EtOH + CH3CH2CH2CO₂H C. NH cat. CH₂SO3H HO AN CENT d. The following is a patented procedur ANO199800
3. Predict the product of radical addition of HBr to the following compounds. A. B. C. D.
Which of the following reagents or reactiion sequences is the best choice for the transformation shown? [You MUST select the correct option to receive credit for this question.] a. Zn(Hg)/HCI b. H₂NNH₂, NaOH, H₂O, A c. NaBH4, CH3OH d. 1. HSCH₂CH₂SH, ZnCl₂; 2. H₂, Raney Ni e. PCC, CH₂Cl₂ OH
What is the major product of a Friedel–Crafts alkylation using the following alkyl chlorides?a. CH3CH2Cl c. CH3CH2CH(Cl)CH3 e. (CH3)2CHCH2Clb. CH3CH2CH2Cl d. (CH3)3CCl f. CH2=CHCH2Cl