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- A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?Consider a flask containing 25.00 mL of 0.100M sodium benzoate (NaC, H5C00). This is titrated with a 0.110 M nitric acid solution from a burette. Given: K, of C,H;co0" is 1.6 x 10-10. Determine the pH of the solution in the flask after 32.00 mL of the acid has been added? You must show any reaction equation(s) that you may think are necessary. Determine the pH of the solution in the flask at the half-way point of the titration.7. The separate samples of nitric and acetic acids are both titrated with a 0.100 M solution of NaOH(aq). (Y) 25.0mL of 1.0 M HNO3(aq) (Z) 25.0 mL of 1.0 M CH3COOH(aq) Determine whether each of the following statements concerning this titration is true or false. (A) A larger volume of NaOH(aq) is needed to reach the equivalence point in the titration of HNO3 (B) The pH at the equivalence point in the HNO3 titration will be lower than the pH at the equivalence point in the CH3COOH titration (C) Phenolphthalein would be a suitable indicator for both titrations Group of answer choices a.) A) False B) True C) True b.) A) False B) False C) True c.) A) False B) True C) False d.) A) True B)True C)True
- A buffer solution contains 0.387 M NaH,PO4 and 0.212 M K2HPO4. Determine the pH change when 0.061 mol HCIO, is added to 1.00 L of the buffer. pH change =| A buffer solution contains 0.229 M CGH;NH3CI and 0.381 M C,H3NH2 (aniline). Determine the pH change when 0.077 mol HCl is added to 1.00 L of the buffer. pH after addition – pH before addition = pH change =| A buffer solution is 0.301 M in HCN and 0.274 M in KCN . If K, for HCN is 4.0×10-10 , what is the pH of this buffer solution?31. (a) Calculate the pH of a mixture containing 0.1 M propanoic acid (CH3CH₂COOH) and 0.050 M sodium propanoate (CH3CH₂COONa) (b) Determine the change in pH that occurs when 0.15 mol solid NaOH is added to 1.00 litre of the buffered solution. 32. (a) Calculate the pH of a buffer solution produced by adding 3.28 g of sodium ethanoate to 1 dm3 of 0.01 M of ethanoic acid (Ka = 1.84x 10-5 at 300K) (b) calculate the pH of this buffer if 10 cm3 of 0.1 M HCl are now addedYou have75.0 mL of a 0.25M solution of a weak base, ethanol amine, HOC2H4NH2, with a kb= 2.8x10^-5. It is to be titrated with 0.50 M HCl. What is the pH of the resulting solutions after the following additions? (a) initial pH (B)after 10.50 mL of HCl have been added (c) 1/2 way to the equivalence point (d) at the equivalence point (E) after 40 mL of HCl has been added (f) what indicator would you choose to signal the endpoint, and WHY?
- (a) Write the net ionic equation for the reaction that occurswhen a solution of hydrochloric acid (HCl) is mixed with asolution of sodium formate (NaCHO2). (b) Calculate theequilibrium constant for this reaction. (c) Calculate theequilibrium concentrations of Na+, Cl-, H+, CHO2-, andHCHO2 when 50.0 mL of 0.15 M HCl is mixed with 50.0 mLof 0.15 M NaCHO2.A buffer solution was prepared that contained 0.60 M hydrogen fluoride, HF (Ka = 7.2 x 104) and 1.00M potassium fluoride, KF. The total volume was 250 mL. (a) What ions and molecules are present in the solution? List them in order of decreasing concentration: Decreasing order of Concentration (b) What is the pH of the buffer solution described above? (c) What is the pH of 100. mL of the buffer solution if you add 100. x 10-3 g of NaOH? Assume negligible change in volume. (USEFUL INFORMATION: MM NaOH = 39.997 g mol-1)A solution is prepared by adding 100 mL of 1.0 M HC,H,O,(aq) to 100 mL of 1.0 M NaC,H,O,(aq). The solution is stirred and its pH is measured to be 4.73. After 3 drops of 1.0 M HCl are added to the solution, the ph of the solution is measured and is still 4.73. Which of the following equations represents the chemical reaction that accounts for the fact that acid was added but there was no detectable change in pH? (A) H;O*(aq) + OH (aq) → 2 H,O(1) (B) H;O*(aq) + CI (aq) → HCI(g) + H,O(1) (C) H,O*(aq) + C,H,O, (aq) → HC,H,0,(aq) + H,0(1) (D) H;O*(aq) + HC,H,O,(aq) - H,C,H,0,*(aq) + H,O()
- 33. Consider a buffer solution that contains 0.45 M HCOOH and 0.55 M NaHCOO. Note that the Ka for formic acid (HCOOH) is 1.8 x 104. (a) Calculate the pH of this buffer solution. pH = (b) Write the net ionic chemical equation that occurs when potassium hydroxide (KOH) (MW of KOH = 56.1 g/mol) is added to the buffer. (c) If 0.260 g of solid KOH is added to 250. mL of this buffer solution, what is the resulting pH of the solution? New pH =(f). Following are the titre values of two students when 25 mL of KIO3(aq) is titrated against Na2S2O3(aq).Titration no. Student 1 Student 21 2 3 24 24.9 25.7 25 24.1 24.0Which student is best in doing titration and why do you say so?(g). Taking the values of best student, calculate the concentration of the solution for which molarity is not known.(Note: first calculate moles of pipet solution in 25 mL, then moles of I2 and then moles of solution of unknown concentration and then its molarity by using average titre)For the titration of an aqueous nitrous acid solution, HNO,(aq), with an aqueous strontium hydroxide solution, Sr(OH)2{aq), what do you expect the pH of the solution to be at the equivalence point? O Basic (pH > 7.00) O Unable to determine the pH of the solution at the equivalence point without additional information O Acidic (pH < 7.00) O Neutral (pH = 7.00)