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- 2. Answer ALL parts a) i. 11. NH₂ C NH₂ NH₂ Br E n NH₂ F Rank the compounds shown above in order of INCREASING basicity (least to most basic). Account for the differences in basicity.6. Discussion 1. Know vapor pressure. 2. How suit the (Pb) of product with the molecular weight? 3. Describe method of acid vapor Pressure.12) Rank these hydrogens as to acidity.
- Explain why using one or two equivalents of NaH results in differentproducts in the following reactions.The powerful electron-withdrawing property of a carbonyl group increases the acidity of a-protons (i.e., protons attached to a carbon that is adjacent to the carbonyl group). The effect varies depending on what else is attached to the carbonyl, and whether there is a second carbonyl group attached to the a-carbon. Rank the structures from highest acidity (lowest pK, value) to lowest acidity (highest pK, value). The acidic hydrogen is indicated in blue in each structure. Highest acidity Lowest acidity Answer Bank H CH3 H CH3 H. CH3 H3C CH3 H3C CH3 H. H. H3C. CH3 H. H 0-CH3The powerful electron-withdrawing property of a carbonyl group increases the acidity of a-protons (i.e., protons attached to a carbon that is adjacent to the carbonyl group). The effect varies depending on what else is attached to the carbonyl, and whether there is a second carbonyl group attached to the a-carbon. Rank the structures from highest acidity (lowest pK, value) to lowest acidity (highest pK, value). The acidic hydrogen is indicated in blue in each structure. Highest acidity Lowest acidity Answer Bank H;C, CH, H- CH, CH H3C CH3 H H. CH3 H3C H. CH3 CH3 H
- The powerful electron-withdrawing property of a carbonyl group increases the acidity of a-protons (i.e., protons attached to a carbon that is adjacent to the carbonyl group). The effect varies depending on what else is attached to the carbonyl, and whether there is a second carbonyl group attached to the a-carbon. Rank the structures from highest acidity (lowest pK, value) to lowest acidity (highest pK, value). The acidic hydrogen is indicated in blue in each structure. Highest acidity Lowest acidity Answer Bank H. H. CH3 H. -CH CH3 H.C H. H3C CH3 H. H. CH H. H,C CH3 H. H. H. -CHHow can th following synthesis be accomplished? Do not give handwriting solution.Draw the major organic product of the Bronsted acid-base reaction. Include all lone pairs and charges as appropriate. Ignore any counterions. NaNHz :O: H