*76. Using data from Table 16.3, calculate the concentrations of Hg²+(aq), HgCl*(aq), and HgCl2(aq) that result when 1.00 L of a 0.100 M Hg(NO3)2 solution is mixed with an equal volume of a 0.100 M HgCl, solution. (Hint: Use the analogy with amphoteric equilibria discussed in Sec- tion 10.8.)
*76. Using data from Table 16.3, calculate the concentrations of Hg²+(aq), HgCl*(aq), and HgCl2(aq) that result when 1.00 L of a 0.100 M Hg(NO3)2 solution is mixed with an equal volume of a 0.100 M HgCl, solution. (Hint: Use the analogy with amphoteric equilibria discussed in Sec- tion 10.8.)
Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter14: Acid- Base Equilibria
Section: Chapter Questions
Problem 97AE: A student intends to titrate a solution of a weak monoprotic acid with a sodium hydroxide solution...
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Transcribed Image Text:TABLE16.3
Formation Constants of Coordination Complexes in Aqueous Solution
K,
K2
K3
K4
K5
K6
Ammines
Ag(NH;);
Co(NH;)*
Cu(NH,);
Ni(NH;)
Zn(NH,),*
1.7 x 107
2.1 X 103
8.2 x 103
2.5 x 104
1.0 X 102
32
8.5
4.4
1.1
0.18
1.1 X 1012
1.0 X 104
2 x 103
5 x 102
90
2+
8 x 10-7
5 X 108
5 x 102
1.3 x 102
40
12
3.3
0.8
12+
1.5 x 102
1.8 x 102
2 x 102
90
Chlorides
1.7 x 103
AgCl,
FeCl,
HgCl
PbCl?
SnCl?
1.8 X 105
1.0 X 102
0.14
28
4.5
0.1
1.1 X 102
1.2 x 1015
5.5 x 106
3 x 106
7
10
25
40
1.5
0.8
0.5
30
32
5.4
0.6
0.3
Hydroxides
зх 1010
3 x 1018
2 x 1011
4 × 1014
5 x 1014
8 x 105
4 X 104
1 x 107
9 x 104
7 X 107
Co(OH);
Cu(OH);
1
5 x 106
4 x 103
2 x 103
6 x 102
5 x 103
30
Ni(OH)3
Pb(OH);
Zn(OH)?
1.1 X 103
2.5 X 104
8 X 106
70
33
Transcribed Image Text:*76. Using data from Table 16.3, calculate the concentrations
of Hg²*(aq), HgCl*(aq), and HgCl2(aq) that result when
1.00 L of a 0.100 M Hg(NO3)2 solution is mixed with an
equal volume of a 0.100 M HgCl, solution. (Hint: Use
the analogy with amphoteric equilibria discussed in Sec-
tion 10.8.)
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