A) -15.8° B) -31.5° C) -63.0° D) +63.0° E) +31.5° 18) In the following reaction, F. NaSH, solvent Br A) The F is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprot B) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar pro C) The F is replaced by a -SH, the reaction goes via SN' and is faster in a polar prot D) The Br is replaced by a -SH, the reaction goes via SN? and is faster in a polar ap E) None of these is true 19) Which of the following species is the most nucleophilic? A) H2O B) F- C) HS- D) NH3

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter20: Carbohydrates
Section: Chapter Questions
Problem 20.58P
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17) If S glutamic acid has a specific rotation of +31.5°, what is the specific rotation of R-
glutamic acid?
A) -15.8° B)-31.5° C) -63.0° D) +63.0° E)+31.5°
10-2-methylbutane
18) In the following reaction,
F.
NaSH, solvent
Br
A) The F is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic so
B) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic sc
C) The F is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic sa
D) The Br is replaced by a-SH, the reaction goes via SN? and is faster in a polar aprotic
E) None of these is true
19) Which of the following species is the most nucleophilic?
A) H2O
B) F-
C) HS-
D) NH3
E) CH3O-
Transcribed Image Text:17) If S glutamic acid has a specific rotation of +31.5°, what is the specific rotation of R- glutamic acid? A) -15.8° B)-31.5° C) -63.0° D) +63.0° E)+31.5° 10-2-methylbutane 18) In the following reaction, F. NaSH, solvent Br A) The F is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic so B) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic sc C) The F is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic sa D) The Br is replaced by a-SH, the reaction goes via SN? and is faster in a polar aprotic E) None of these is true 19) Which of the following species is the most nucleophilic? A) H2O B) F- C) HS- D) NH3 E) CH3O-
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