A + B à 2C + D , which obeys the rate equation: d[D]/dt k[A]a[B]b [A] (M) [B] (M) d[D]/dt (M/s) 0.300 0.300 1.31×105 0.600 0.300 3.69×10−5 0.300 0.600 1.85×10−5 What is the overall reaction order and orders of A and B. Calculate the rate constant K.

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.32PAE: 11.32 The following experimental data were obtained for the reaction 2A + 3 B—C + 2D [A](mol L 1)...
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  1. A + B à 2C + D , which obeys the rate equation: d[D]/dt k[A]a[B]b

[A] (M)

[B] (M)

d[D]/dt (M/s)

0.300

0.300

1.31×105

0.600

0.300

3.69×10−5

0.300

0.600

1.85×10−5

What is the overall reaction order and orders of A and B. Calculate the rate constant K. 

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