A dilute solution of weak (1,1)-electrolyte contains both neutral ion pairs and ions in equilibrium (AB =A* + B¯). Prove that molar conductivities (A) are related to the degree of ionization (a) by the equations: Given that: A = a4 + A_ = Ao – K(ac)'/2 and x = (1+ + A_)Cion = (1, + a_)ac Where di denotes molar ionic conductivity at infinite dilution for ion i; ^, is the molar conductivity of infinite dilution and K is the constant in Kohlrausch's law; K denotes electrolytic conductivity and c denotes concentration.
A dilute solution of weak (1,1)-electrolyte contains both neutral ion pairs and ions in equilibrium (AB =A* + B¯). Prove that molar conductivities (A) are related to the degree of ionization (a) by the equations: Given that: A = a4 + A_ = Ao – K(ac)'/2 and x = (1+ + A_)Cion = (1, + a_)ac Where di denotes molar ionic conductivity at infinite dilution for ion i; ^, is the molar conductivity of infinite dilution and K is the constant in Kohlrausch's law; K denotes electrolytic conductivity and c denotes concentration.
Chapter10: Effect Of Electrolytes On Chemical Equilibria
Section: Chapter Questions
Problem 10.8QAP
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