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- The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?Melamine, used as a fire retardant and a component of the writing surface of white boards, can be prepared from s-trichlorotriazine through a series of SNAr reactions with ammonia. The first substitution takes place rapidly at room temperature. The second substitution takes place near 100 °C, and the third substitution requires even higher temperature and pressure. Provide an explanation fatr this reactivity.Propose a mechanism.
- Identify the suitable reagents for the given reaction and arrange them accordingly. 1 OH OEt 2 OEt OEt O 1) EtOH, H₂SO4; 2) EtOH, H₂SO4 O 1) EtONa followed by H₂O; 2) TsCl/py followed by EtONa O 1) EtONa followed by H₂O; 2) NaH followed by EtBr O 1) EtOH, H₂SO4; 2) NaH followed by EtBr O 1) EtOH, H₂SO4; 2) TsCy followed by EtONa3) Propose a mechanism for the following reaction. HO H2SO4Identify the reagents needed to carry out each reaction. Br KOCCCH,), COH NaH LOTS TSCI pyridine Br TSOH NBS HBr CI, Br LOH 'OH CI
- What is the major product formed in the following reaction? 1) ВНз THF major product? 2) Н202, NaOH HO. 1) 2) OH OH 3) 4) HOHQ6. Propose a mechanism for the following reaction: Br CH3O + BrDetermine the reagents required for the following syntheses. More than one reaction is likely required. a) b) c) d) OH OH olm NH₂ MeO NHMe Me. Me OH OH
- N 3 5 Predicate the products of each reaction: Aldehydes + Ketones CH₂-C-OCH, CH;CH + HC=N =O + H₂NCH₂ OH O + H₂O H H₂SO4 HgSO4 2 H₂ Ni NaCN + NaBH₂ H+ Zn (Hg), HCIThe reaction of an alkene with diazomethane forms a cyclopropane ring. Propose a mechanism for the reaction.c) Propose a mechanism for this reaction. BF3 Но HO.