A student was given from the list of the compounds below A, B and D blindly and asked to identify them all. He treated each of them with Brady's reagent (2,4-ditrophenylhydrazine) and isolated a bright yellow compound for one of them, but the other two gave false negatives. The student reasoned that the false negatives may be due to sterics and, on further thinking, it dawned on him that he might be able to rule out one of the false negatives with the haloform test. What compound did he find compatible with the haloform test? That compound did indeed give a false negative in the Brady test. Which of the other two was positive in the Brady test? B он A = haloform B = Brady A= haloform D = Brady B = haloform A = Brady B = haloform D = Brady D = haloform A = Brady D = haloform

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A student was given from the list of the conmpounds below A, B and D blindly and asked to identify them all.
He treated each of them with Brady's reagent (2,4-ditrophenylhydrazine) and isolated a bright yellow
compound for one of them, but the other two gave false negatives. The student reasoned that the false
negatives may be due to sterics and, on further thinking, it dawned on him that he might be able to rule out
one of the false negatives with the haloform test. What compound did he find compatible with the haloform
test? That compound did indeed give a false negative in the Brady test. Which of the other two was positive in
the Brady test?
A = haloform
B = Brady
A = haloform
D = Brady
B = haloform
A = Brady
B = haloform
D = Brady
D = haloform
A = Brady
D = haloform
B = Brady
Transcribed Image Text:A student was given from the list of the conmpounds below A, B and D blindly and asked to identify them all. He treated each of them with Brady's reagent (2,4-ditrophenylhydrazine) and isolated a bright yellow compound for one of them, but the other two gave false negatives. The student reasoned that the false negatives may be due to sterics and, on further thinking, it dawned on him that he might be able to rule out one of the false negatives with the haloform test. What compound did he find compatible with the haloform test? That compound did indeed give a false negative in the Brady test. Which of the other two was positive in the Brady test? A = haloform B = Brady A = haloform D = Brady B = haloform A = Brady B = haloform D = Brady D = haloform A = Brady D = haloform B = Brady
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