(a) Suppose that CaO is added as an impurity to Li2O. If the Ca2+ substitutes for Li+ , what kind of vacancies would you expect to form? How many of these vacancies are created for every Ca2+ added? (b) Suppose that CaO is added as an impurity to CaCl2 . If the O2– substitutes for Cl– , what kind of vacancies would you expect to form? How many of these vacancies are created for every O2– added?

Chemistry & Chemical Reactivity
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ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter20: Environmental Chemistry-earth's Environment, Energy, And Sustainability
Section20.7: Green Chemistry And Sustainability
Problem 2.1ACP: Assume that a sample of hard water contains 50. mg/L of Mg2+ and 150 mg/L of Ca2+, with HCO3 as the...
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(a) Suppose that CaO is added as an impurity to Li2O. If the Ca2+ substitutes for Li+ , what kind of vacancies would you expect to form? How many of these vacancies are created for every Ca2+ added? (b) Suppose that CaO is added as an impurity to CaCl2 . If the O2– substitutes for Cl , what kind of vacancies would you expect to form? How many of these vacancies are created for every O2– added?

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