A voltaic cell consists of a Pb/Pb2+ half-cell and a Cu/Cu2+ half-cell at 25 ∘C. The initial concentrations of Pb2+ and Cu2+ are 0.0520 M and 1.60 M , respectively.  a) What is the initial cell potential? Express your answer using two significant figures. b) What is the cell potential when the concentration of Cu2+ has fallen to 0.230 M ? Express your answer using two significant figures. c) What is the concentration of Pb2+ when the cell potential falls to 0.370 V ? Express your answer using three significant figures.

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter19: Principles Of Chemical Reactivity: Electron Transfer Reactions
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Problem 94GQ: A voltaic cell is constructed in which one half-cell consists of a silver wire in an aqueous...
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A voltaic cell consists of a Pb/Pb2+ half-cell and a Cu/Cu2+ half-cell at 25 ∘C. The initial concentrations of Pb2+ and Cu2+ are 0.0520 M and 1.60 M , respectively. 

a) What is the initial cell potential? Express your answer using two significant figures.

b) What is the cell potential when the concentration of Cu2+ has fallen to 0.230 M ? Express your answer using two significant figures.

c) What is the concentration of Pb2+ when the cell potential falls to 0.370 V ? Express your answer using three significant figures.

 

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