(a) What is the percentage of MnO2 in a pyrolusite ore if a sample weighing 0.4000 g is treated with a 0.6000 g of pure H,C,O4.2H2O and dilute H,SO4 and after reduction has taken place (MnO2 + H2C204 + 2H* → Mn2+ + 2CO2 + 2H,O), the excess oxalic acid requires 26.26 mL of 0.1000 N KMnO4 for titration? (b) If pure As,O, were used instead of oxalic acid, how many grams would be required in order for the other numerical data to remain the same?

Chemistry: The Molecular Science
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ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
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Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
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(a) What is the percentage of MnO, in a pyrolusite ore if a sample weighing 0.4000 g is treated with
a 0.6000 g of pure H2C2O4.2H20 and dilute H,SO4 and after reduction has taken place
(MnO2 + H2C204 + 2H* → Mn2+ + 2CO, + 2H,O), the excess oxalic acid requires 26.26 mL of
0.1000 N KMnO4 for titration? (b) If pure As,03 were used instead of oxalic acid, how many grams
would be required in order for the other numerical data to remain the same?
Transcribed Image Text:(a) What is the percentage of MnO, in a pyrolusite ore if a sample weighing 0.4000 g is treated with a 0.6000 g of pure H2C2O4.2H20 and dilute H,SO4 and after reduction has taken place (MnO2 + H2C204 + 2H* → Mn2+ + 2CO, + 2H,O), the excess oxalic acid requires 26.26 mL of 0.1000 N KMnO4 for titration? (b) If pure As,03 were used instead of oxalic acid, how many grams would be required in order for the other numerical data to remain the same?
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