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- The following compounds are given to you:2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane(i) Write the compound which is most reactive towards SN2 reaction.(ii) Write the compound which is optically active.(iii) Write the compound which is most reactive towards P-elimination reaction.(b) The activating and deactivating groups could affect the position(s) of the next incoming group(s) to the benzene ring. Based on the structure below, analyze and explain the group(s) on the benzene ring is activating or deactivating group. Then, identify the product(s) formed from the following reactions. NH, CC, CH;CH,COCI AICI, (i) NH, HNO, H,SO, (ii) H Br AICI, (iii) Page 3 of 42. Draw the structures of the products that would result from the following reactions. Ph Ph (a) (c) Ph Ph co is also produced. Ph Ph. (b) O+ Ph-C C-Ph (d) Ph 10 Ph co is also produced. Benzyne adds to the 9, 10 position on anthracene.
- Which of the following compounds will form a yellow solid when dissolved in a basic, aqueous solution of I2?(a) butanoic acid; (b) pentan-2-one; (c) pentan-3-one; (d) cyclohexanone; (e) pentanalb) Listed below are several hypothetical nucleophilic substitution reactions. None is synthetically useful because the product indicated is not formed at an appreciable rate. In each case provide an explanation for the failure of the reaction to take place as indicated. OMe HO + OMe + OH HO + CH; OHBr Brz CH3 CH3 H3C CH2CI2 H3C Br Electrophilic addition of bromine, Br2; to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH,Cl). In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br: :Br: .CH3 H3C H3C CH3 Br:
- Illustrate the resonance effect of the methoxy group -OCH3, on the structure of the benzene ring. Draw all the oissuvke resonance forms of methoxybenzene, including the hybrid Based on the structures, explain how the presence of the -OCH3 group affects: (i) the reactivity of the benzene ring towards electrophilic attack (ii) the orientation or point of attack of an incoming electrophilic reagent on the benzene ring.Help ASAP Illustrate the resonance effect of the methoxy group -OCH3, on the structure of the benzene ring. Do this by writing all the possible resonance forms for methoxybenzene, including the hybrid. Based on your structures, explain how the presence of the -OCH3 group affects: (i) the reactivity of the benzene ring towards electrophilic attack; (ii) the orientation or point of attack of an incoming electrophilic reagent on the benzene ring.(c) Hydrolysis of the haloalkane shown below results in the formation of two alcohols B and C that are stereoisomers of each other. Give the structures of the alcohols B and C and propose a mechanism for their formation ensuring that you explain the stereochemical outcome observed. H3CH2C CH3 H20, heat Br H. B + C
- Q6. Enolates and their surrogates. (a) Rank the acidity of the following compounds from LEAST (left) to MOST (right) by entering the corresponding numbers in the boxes provided. 1 4 2 NaNH, CO₂Me 5 3 CHO (b) Complete the following reaction products by adding the correct bonds, atoms and charges, as necessary.Which of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4In EAS bromination reactions, a -CON(CH3)2 substituent on the aromatic ring is: an activator and an o,p-director. a deactivator and a m-director. an activator and a m-director. the substituent catalyzes the 1,2 addition of bromine across the double bond. a deactivator and an o,p-director. G