(c) [5 pts] Sketch a graph of the entropy of the van der Waals gas and the entropy of the perfect gas as a function of Vm for b = 1. What happens as b→ 0? Take n = 1 and plot S/nR. (d) [5 pts] Explain the intuition for the graph in (c) using the Boltzmann entropy and the number of microstates.

(c) [5 pts] Sketch a graph of the entropy of the van der Waals gas and the entropy of the perfect gas as a function of Vm for b = 1. What happens as b→ 0? Take n = 1 and plot S/nR. (d) [5 pts] Explain the intuition for the graph in (c) using the Boltzmann entropy and the number of microstates.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter1: Gases And The Zeroth Law Of Thermodynamics

Section: Chapter Questions

Problem 1.65E: Determine an expression for V/T p, n in terms of and . Does the sign on the expression make sense...

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Question

(c) [5 pts] Sketch a graph of the entropy of the van der Waals gas and the entropy of the perfect
gas as a function of Vm for b = 1. What happens as b→ 0? Take n = 1 and plot S/nR.
(d) [5 pts] Explain the intuition for the graph in (c) using the Boltzmann entropy and the number
of microstates.

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