Calculate the pH of a buffer solution which contains the weak monoprotic acid, propanoic acid (CH³CH₂COOH), in concentration 0.1 mol/L and sodium propanoate in concentration 0.05 mol/L. Ką of propanoic acid is 1.26 x 10¹5 mol/L. Give equations to show how the above solution fulfills its buffer function.

Calculate the pH of a buffer solution which contains the weak monoprotic acid, propanoic acid (CH³CH₂COOH), in concentration 0.1 mol/L and sodium propanoate in concentration 0.05 mol/L. Ką of propanoic acid is 1.26 x 10¹5 mol/L. Give equations to show how the above solution fulfills its buffer function.

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria

Section: Chapter Questions

Problem 27PS: Phenol, C6H5OH, is a weak organic acid. Suppose 0.515 g of the compound is dissolved in enough water...

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Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.
Phenol, C6H5OH, is a weak organic acid. Suppose 0.515 g of the compound is dissolved in enough water to make 125 mL of solution. The resulting solution is titrated with 0.123 M NaOH. C6H5OH(aq) + OH(aq) C6H5O(aq) + H2O() (a) What is the pH of the original solution of phenol? (b) What are the concentrations of all of the following ions at the equivalence point: Na+, H3O+, OH, and C6H5O? (c) What is the pH of the solution at the equivalence point?
A buffer is made by adding 0.18 mol/L of sodium propanoate (NaPr) to 0.12 mol/L solution of propanoic acid (HPr, K«= 1.3 x 105). Assume the volume of the solution to be 1.0 L. a) Write the chemical equation for the acid hydrolysis reaction. | b) What is the acid-base conjugate pair that governs the pH of the buffer? c) Calculate the pH of the buffer. Be sure to justify and validate any approximations used.
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33. Consider a buffer solution that contains 0.45 M HCOOH and 0.55 M NaHCOO. Note that the Ka for formic acid (HCOOH) is 1.8 x 104. (a) Calculate the pH of this buffer solution. pH = (b) Write the net ionic chemical equation that occurs when potassium hydroxide (KOH) (MW of KOH = 56.1 g/mol) is added to the buffer. (c) If 0.260 g of solid KOH is added to 250. mL of this buffer solution, what is the resulting pH of the solution? New pH =
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