Calculate the pH of the following buffer solutions: (a) a solution made by dissolving 2.733 g KH2PO4 and 4.508 g K2HPO4 in water to give 250. mL of solution. Stepwise acid dissociation constants for phosphoric acid may be found in your textbook. (b) a solution made by mixing 35.00 mL 0.24 M C6H5NH2  with 15.00 mL 0.19 M C6H5NH3Cl. The base dissociation constant Kb is 4.00 x 10^-10 for C6H5NH2. Assume that the final volume is the sum of the volumes of the two solutions that are mixed.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 14QAP: A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to...
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Calculate the pH of the following buffer solutions:


(a) a solution made by dissolving 2.733 g KH2PO4 and 4.508 g K2HPO4 in water to give 250. mL of solution. Stepwise acid dissociation constants for phosphoric acid may be found in your textbook.

(b) a solution made by mixing 35.00 mL 0.24 M C6H5NH2  with 15.00 mL 0.19 M C6H5NH3Cl. The base dissociation constant Kb is 4.00 x 10^-10 for C6H5NH2. Assume that the final volume is the sum of the volumes of the two solutions that are mixed. 

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