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Calculate the solubility of Cd,Fe(CN), in a 0.0333 M solution of Mg(CIO,), using molar concentrations. Use the linear interpolation of experimental data in Table 10- 2 if necessary. 4- Cd,Fe(CN), (5) 2 Cd + Fe(CN), K = 3.2 x -17 10 ds,

Calculate the solubility of Cd,Fe(CN), in a 0.0333 M solution of Mg(CIO,), using molar concentrations. Use the linear interpolation of experimental data in Table 10- 2 if necessary. 4- Cd,Fe(CN), (5) 2 Cd + Fe(CN), K = 3.2 x -17 10 ds,

Appl Of Ms Excel In Analytical Chemistry
Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter6: The Systematic Approach To Equilibria: Solving Many Equations
Section: Chapter Questions
Problem 10P
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Calculate the solubility of Cd, Fe(CN), in a 0.0333 M solution of Mg(CIO,), using molar concentrations. Use the linear interpolation of experimental data in Table 10- 2 if necessary. 2+ 2 Cd + Fe(CN), 4- Cd,Fe(CN), (s) Kn = 3.2 x sp -17 10 TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Coefficient at Indicated lonic Strength Jon H,O Li. CH,COO Na", 10,5. HSO,. Hco, H,PO,. HAsO,. OAC OH ,F, SCN, HS , CIO,, CIO, , BrO, , 10, , Mno, K*. CI, Br.1. CN". NO,. NO,, HCOO- Rb", C, TI, Ag'. NH," M, Be C. Cu*, Za, Sn“, Mn, Fe, Ni, Co". Phthalate S, Ba", Ca", Hg", s- Pb*, CO,, So,.COF Hg", So,, 5,0,, Cr. HPO, Al*. Fe", C*, La, Ce PO,", FE(CN), Th", Z", Ce", Sn Fe(CN), 0.001 0.005 0.01 0.05 0.1 0.9 0.967 0.934 0.913 0.85 0.83 0.6 0.966 0.930 0.907 0.83 0.80 0.4-0.45 0,965 0.927 0.902 0,82 0.77 0.35 0.965 0.926 0.900 0.81 0.76 0.3 0.965 0.925 0.899 0.81 0.75 0.25 0.965 0.925 0.897 0.80 0.75 0.8 0.872 0.756 0.690 0.52 0.44 0.6 0.870 0.748 0,676 0.48 0.40 0.5 0.45 0.40 0.869 0.743 0.668 0.46 0.38 0.868 0.741 0.665 0.45 0.36 0.867 0.737 0.738 0.661 0.44 0.35 0.9 0.540 0.443 0.24 0.18 0.4 0.726 0.505 0.394 0.16 0.095 1.1 0.587 0.348 0.252 0.10 0.063 0.5 0.569 0,305 0.200 0.047 0.020 Source: Reprinted (adapted) with permisioni from J. Kielland, /. An. Chem. Svc., 1937, 59, 1675, DOI: 10.1021/ja01288al132. Copyright 1937 American Chemical Society.
Transcribed Image Text:Calculate the solubility of Cd, Fe(CN), in a 0.0333 M solution of Mg(CIO,), using molar concentrations. Use the linear interpolation of experimental data in Table 10- 2 if necessary. 2+ 2 Cd + Fe(CN), 4- Cd,Fe(CN), (s) Kn = 3.2 x sp -17 10 TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Coefficient at Indicated lonic Strength Jon H,O Li. CH,COO Na", 10,5. HSO,. Hco, H,PO,. HAsO,. OAC OH ,F, SCN, HS , CIO,, CIO, , BrO, , 10, , Mno, K*. CI, Br.1. CN". NO,. NO,, HCOO- Rb", C, TI, Ag'. NH," M, Be C. Cu*, Za, Sn“, Mn, Fe, Ni, Co". Phthalate S, Ba", Ca", Hg", s- Pb*, CO,, So,.COF Hg", So,, 5,0,, Cr. HPO, Al*. Fe", C*, La, Ce PO,", FE(CN), Th", Z", Ce", Sn Fe(CN), 0.001 0.005 0.01 0.05 0.1 0.9 0.967 0.934 0.913 0.85 0.83 0.6 0.966 0.930 0.907 0.83 0.80 0.4-0.45 0,965 0.927 0.902 0,82 0.77 0.35 0.965 0.926 0.900 0.81 0.76 0.3 0.965 0.925 0.899 0.81 0.75 0.25 0.965 0.925 0.897 0.80 0.75 0.8 0.872 0.756 0.690 0.52 0.44 0.6 0.870 0.748 0,676 0.48 0.40 0.5 0.45 0.40 0.869 0.743 0.668 0.46 0.38 0.868 0.741 0.665 0.45 0.36 0.867 0.737 0.738 0.661 0.44 0.35 0.9 0.540 0.443 0.24 0.18 0.4 0.726 0.505 0.394 0.16 0.095 1.1 0.587 0.348 0.252 0.10 0.063 0.5 0.569 0,305 0.200 0.047 0.020 Source: Reprinted (adapted) with permisioni from J. Kielland, /. An. Chem. Svc., 1937, 59, 1675, DOI: 10.1021/ja01288al132. Copyright 1937 American Chemical Society.
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