Calculate the volume occupied by 1.00 mol N2 using the van der Waals equation expanded into the form of a virial expansion at (a) its critical temperature, (b) its Boyle temperature. Assume that the pressure is 10 atm throughout. At what temperature is the behaviour of the gas closest to that of a perfect gas? Use the following data: Tc = 126.3 K, TB = 327.2 K, a = 1.390 dm6 atm mol−2, b = 0.0391 dm3 mol−1.

Chemistry: The Molecular Science
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Chapter8: Properties Of Gases
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Calculate the volume occupied by 1.00 mol N2 using the van der Waals equation expanded into the form of a virial expansion at (a) its critical temperature, (b) its Boyle temperature. Assume that the pressure is 10 atm throughout. At what temperature is the behaviour of the gas closest to that of a perfect gas? Use the following data: Tc = 126.3 K, TB = 327.2 K, a = 1.390 dm6 atm mol−2, b = 0.0391 dm3 mol−1.

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