(CH3)3CO- is a base that can be made from (CH3)3OH (pKa = 18). Using curved arrow formalism, draw a reaction of this base reacting with NH3 (pKa = 36). Show the products. Which way will be equilibrium lie? Explain.
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(CH3)3CO- is a base that can be made from (CH3)3OH (pKa = 18). Using curved arrow formalism, draw a reaction of this base reacting with NH3 (pKa = 36). Show the products. Which way will be equilibrium lie? Explain.
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- Draw curved arrows to indicate the movement of electrons in the following reaction. H H HỌ: Arrow-pushing Instructions HỌ: NOC XT H H---- H H C-CI 1 H CI / HO-C- A HO-C H H H H :CI: :CI:2 Write the IUPAC name for each compound. Ο COC-M (a) HV Ο 0 || (d) H₂N- C (b) CH₂(CH₂),COCH, OTT HO noitos2) alodo d diw sobirbydaA to noilo ono evig of alcools dikw 39891 abitbydA (8.81 (c) CH₂(CH₂)4CNHCH, no bae totes me to slom 0 O CNH₂ با нио но но но HOOH + HOOO HO HOOOH OHO.HOOD HO || (e) CH₂CO-A iw sobixbydnA to noltoso. driw do A (D681 moitoo@) aoniMA "I w bn shomme a onions to solomeowths of elom ono bas shima Joubo aviy oj vig OH OHO bertiup bios biydisororesidenten (f) CH3CHCH₂COCH₂CH36. Complete the following reaction scheme (g) CH H3C. 1) 9-BBN CH 2) H-О, NaOH (h) H20, H,SO4. HØSO4 (i) 1) BH3 2) H2O,, NaOH
- 5. A. B. C. D. Draw all products (substitution and elimination), including stereoisomers, in each reaction. Label as SN1, SN2, E1, E2. CI J CI & H H HCC₂ Ph ·!|||D III... Br Ph KOH CH₂OH DBU DBNDid you first add the H2O(l) on the right side of the equaton and then added the 2HO- on the left side and multiplied CIO2 on the left side by 2?4.) Draw curved arrows for the reactions below. Make sure to draw in lode pairs where needed! H-O-H H-O-H до HON H OH + H-O- Н-О H-O H₂N* HO OH H-0-Н
- Rank the following carbonyls according to their electrophilicity (1 = most) OEt O of O NEt₂ O CF3 O(5 points) Identify the electrophile and the nucleophile in each of the following reaction steps and then draw curved arrows to illustrate the bond-making and bond-breaking processes. C'H;CH CH, + Н-Br CНCH -СH + BrQ6. Fill in the blanks left in each of the following syntheses: Example: OH di-ar Find the flow(s): OH H₂0⁰ CH₂OH, H OH Mair NHANH, KOH OH
- The reaction shown below yields the given product. True False OH + NH₂ DCC NH₂The best way to accomplish the following reaction is: CH3 x CH3 (a) Hg(OAc)2, H₂O; NaBH4, HO™ (b) BH3 THF; H₂O₂, HO OH CH3 CH3 (c) H+, H₂O (d) 1. MCPBA; 2. H3O+6. The product(s) of the following reaction dd blow di CH2-CH2 excess HBr is/are: CH2 CH2 heat Od Al () (A od Ocf D (CHPPCOK (CHPCON G)D CH;CH2OCH,CH3 HO CH;CH,CH,CH,OH and CH;CH,CH2CH,Br II H t mol boumol toubong soinm od o CH2-CHBR HO CH2 CH2 BrCH-CH,CH-Cн,ОН and BrCH,CH,CH-CH,Br CityCHCH COM III IV A) I B) П O II D) IV E) None of these HO CH CH'OH