Ethyl benzoate PhCO₂Et has these peaks in its 13C NMR spectrum: 17.3, 61.1, 100- 150 (four peaks) and 166.8 ppm. Which peak belongs to which carbon atom? Draw the structure of ethyl benzoate and clearly identify each carbon with its corresponding chemical shift.

Ethyl benzoate PhCO₂Et has these peaks in its 13C NMR spectrum: 17.3, 61.1, 100- 150 (four peaks) and 166.8 ppm. Which peak belongs to which carbon atom? Draw the structure of ethyl benzoate and clearly identify each carbon with its corresponding chemical shift.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter13: Structure Determination: Nuclear Magnetic Resonance Spectroscopy

Section13.SE: Something Extra

Problem 51AP: Assign as many resonances as you can to specific carbon atoms in the 13C NMR spectrum of ethyl...

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Concept explainers

NMR Spectroscopy

NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra of visible light and all bands of electromagnetic radiation is called spectroscopy.

Question

Ethyl benzoate PhCO₂Et has these peaks in its 13C NMR spectrum: 17.3, 61.1, 100-
150 (four peaks) and 166.8 ppm. Which peak belongs to which carbon atom? Draw the
structure of ethyl benzoate and clearly identify each carbon with its corresponding
chemical shift.

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