For each of the following pairs of reaction diagrams, identify which of the pairs is catalyzed: (a) 50 50 45 40 35 30 45 40 35 30 25 20 15 15 10 10 Extent of reaction Extent of reaction (a) (b) (b) 50 50 45 40 45 40 35 30 25 15 15 10 10 Extent of reaction Extent of reaction (a) (b) Energy (kJ) Energy (kJ) Energy (kJ) Energy (kJ)
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- Calculate So values for the following reactions by using tabulated So values from Appendix C.(a) 2 NOCl(g) Æ 2 NO(g) + Cl2(g)(b) Be(OH)2(s) BeO(s) + H2O(g)(c) HCl(g) + NaOH(aq) NaCl(s) + H2O(l)(d) 2 CH4(g) C2H6(g) + H2(g)What will happen to the equilibrium, NaHCO3(s)Na2CO3(s) + CO2(g) + H2O(g);Ho = 136 kJ when: (a) the temperature is decreased(b) the volume of the container is increased (c) water vapor is removed(d) additional Na2CO3 is added(e) pressure of CO2 is increasedCompare the TWO reaction energy profiles shown below. (A) Reaction Progress Reaction Progress (a) A chemical reaction is used as the basis of the heat packs that are used for first aid. Which reaction profile, A or B, best represents the enthalpy change for the reaction in this system? Explain the reasons for your choice. Profile (b) Identify the reaction profile (A or B) that represents the progress of the following reaction: 2NO(g) + O₂(g) → 2NO₂(g) ΔΗΘ = -113.14 kJ Profile (c) Calculate the heat energy transferred when when 100.0 g of nitrogen monoxide gas reacts with excess oxygen through the reaction given in part (b). Energy Energy (B)
- Which of the following reactions represents an endothermic reaction? 2 SO3 (3) + 198 kJ → 2 SO2 (3) + O2 (g) 02 C,H6 + 702 2 (g) 4 CO2(2) + 6 H2O (1)+ (g) 3120 kJ O CHA (3) + 2O2 (8) → CO2 () + 2H2O (g) + 890 kJ 2 SO2 (e) 2S + 202 () +376 kJ (s) insert %23 2 "3 4 E R SID G H J K pause alt ト LL LLIwhat is delta Hr for the reaction 3NH3 (g) + 3.75 (g) - 3NO(g) + 4.5 H20 (g) delta Hr = -904.7KJ 4NH3 (g) + 5O (g) ----> 4NO(g) + 6 H20 (g) delta Hr= -904.7 JKWhat is AG rxn for the following reaction? 3NO2(g) + H₂O() → 2HNO3() + NO(g) Substance AGf (kJ/mol) H₂O(1) HNO3(1) NO(g) NO2(g) -237.2 -79.9 86.7 51.8
- 35R) AH for the reaction IF5 (g) → IF3 (g) + F2 (g) is kJ, give the data below. IF (g) + F2 (g) → IF3 (g) AH = -390 kJ IF (g) + 2F2 (g) → IF5 (g) AH =-745 kJ A) +355 B) -1135 C) +1135 D) +35 E) -35. vanAartis aal i. Based on Textbook 2.35-2.37: Orthopedic surgeons use bone “cement" to set artificial hip implants in place. This "“cement" is methyl methacrylate that is polymerized during the surgery. However, surgeons notice a substantial amount of heat evolution from the reaction. Calculate the reaction energy if a surgeon uses 20g of methyl methacrylate glue (the precursor) to set a given hip implant. The polymerization reaction is given for you. free radical CH3 c=c CH3 +CH;-C c=0 H vinyl polymerization C=0 CH3 CH3Given the individual step reactions:2O3(g) -> 3O2(g) ΔH = -427 kJO2(g) -> 2O(g) ΔH = +495 kJNO(g) + O3(g) -> NO2(g) + O2(g) ΔH = -199 kJCalculate the ΔH for the reactionNO(g) + O(g) -> NO2(g) a. -233 kJ b. -257 kJ c. -245 kJ d. -215 kJ
- Which among the following represents the subshell with n=5 and l=3? 5p 5d 4d 5fThe following diagram represents the endothermic reaction at equilibrium at 25°C: heat + A(g) = 2B(g) The temperature is increased to 50°C. Which of the following diagrams would represent the system once equilibrium is reestablished? Select the single best answer. O O (b) (c) =A =B (a)Which of the following reactions will release the most energy? O CH41) + O2(1) CO(g) + 2H20(g) O CHA(1) + O2() CO2() + 2H20(1) O CHA(g) + O2lg) CO2(g) + 2H2O(g) O CHA(g) + O2(g) CO2() + 2H2O(1)