How would the calculated value of pKa of the unknown acid be affected (higher, lower,  or no change) if the following errors occurred? Briefly explain why in each case. The pH meter was incorrectly calibrated to read lower than the actual pH. During the titration several drops of NaOH missed the reaction beaker and fell onto the bench top. In part B of the procedure the acid was dissolved in 75 mL of distilled water rather than the 50 mL called for in the procedure.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section16.10: The Lewis Concept Of Acids And Bases
Problem 2.2ACP: Other solvents also undergo autoionization. (a) Write a chemical equation for the autoionization of...
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How would the calculated value of pKa of the unknown acid be affected (higher, lower,  or no change) if the following errors occurred? Briefly explain why in each case.

  1. The pH meter was incorrectly calibrated to read lower than the actual pH.
  2. During the titration several drops of NaOH missed the reaction beaker and fell onto the bench top.
  3. In part B of the procedure the acid was dissolved in 75 mL of distilled water rather than the 50 mL called for in the procedure.
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