In a study of the rearrangement of cyclopropane to propene at 500 °C (CH2)3 CH3CH=CH2 the concentration of (CH2)3 was followed as a function of time. It was found that a graph of In[(CH2)3] versus time in seconds gave a straight line with a slope of -1.02×10-3 sl and a y-intercept of -2.77 Based on this plot, the reaction is v order in (CH2)3 and the rate constant for the reaction is s-1 zero first Submit Answer Try Another V second item attempts remaining

In a study of the rearrangement of cyclopropane to propene at 500 °C (CH2)3 CH3CH=CH2 the concentration of (CH2)3 was followed as a function of time. It was found that a graph of In[(CH2)3] versus time in seconds gave a straight line with a slope of -1.02×10-3 sl and a y-intercept of -2.77 Based on this plot, the reaction is v order in (CH2)3 and the rate constant for the reaction is s-1 zero first Submit Answer Try Another V second item attempts remaining

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter21: Benzene And The Concept Of Aromaticity

Section: Chapter Questions

Problem 21.43P: Following is an equation for iodination of toluene. This reaction does not take place. All that...

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Describe the reaction mechanism for the hydrolysis of 2-bromo-2-methylpropane [CH3C(CH3)2Br] with aqueous hydroxide ions (OH-).The description should be detailed and must include the type of bond fission that takes place. You may sketch and insert suitable diagrams to aid your description if you wish
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The aerobic oxidation of para-xylene to terephthalic acid is an important process in industrial chemistry. Discuss why the oxidation of the second methyl group requires harsher conditions than the oxidation of the first methyl group. You should accurately reference all your bibliographic material.
Following is an equation for iodination of toluene. This reaction does not take place. All that happens under experimental conditions for the formation of radicals is initiation to form iodine radicals, I , followed by termination to reform I2. How do you account for these observations?
Use the data provided below to estimate (a) the temperature at which CaCO3 decomposes spontaneously assuming ArH and ArS remain unchanged at the temperature region of interest. СаСОз (s) --> СaO (s) + CО2 (g) kJ mol-1 Jк1 mol-1 AfHo -1207 -635 -394 Smo 93 40 214 Tspont. >= K. 3 s.f.
؟ مثلا مششكر ل محمد (A A) H-Bri -B) вз ултива хотоо халото ~0% Ž a.) Given our discussions of this mechanism express in a reaction coordinate diagram the two reactions above. * Please exaggerate scale for clarity * AG 99.9999% +HBr
With regards to this, I have been reading journals about activated carbon that is being modified. Now, the activated carbon is modified through acid treatment, and sulfuric acid is added to it. The result was, that there is a presence of SO3-, C=O=C, and C=O on the modified activated carbon. They concluded that the process of sulfonation on the activated carbon treated with sulfuric acid took place. Can you explain the chemistry/mechanism/reaction that happened? Explain in detail and clearly. Thank you so much!
21. (a) Using the information given in Sections 3-6 and 3-7, write the products of the radical monochlorination of (i) pentane and (ii) 3- methylpentane. (b) For each, estimate the ratio of the isomeric monochlorination products that would form at 25°C. 25°C. (c) Using the bond strength data from Table 3-1, determine the AH°AH values of the propagation steps for the chlorination of 3-methylpentane at C3. What is the overall AH°AH® value for this reaction?
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