In the Cr* oxidation of cyclohexanols, it is generally true that sterically hindered alcohols react faster than unhindered alcohols. Which of the following alcohols should be oxidized more rapidly? (CH),C (CHa),C .OH

In the Cr* oxidation of cyclohexanols, it is generally true that sterically hindered alcohols react faster than unhindered alcohols. Which of the following alcohols should be oxidized more rapidly? (CH),C (CHa),C .OH

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry

Section4.SE: Something Extra

Problem 62AP: Alcohols undergo an oxidation reaction to yield carbonyl compounds on treatment with CrO3. For...

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Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

In the Cr®* oxidation of cyclohexanols, it is generally true that sterically hindered alcohols react faster than unhindered alcohols.
Which of the following alcohols should be oxidized more rapidly?
(CHa),C=
(CH3)3C-
OH

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