In the current experiment, we will use a different electrophile (the tert.-butyl cation) to alkylate 1,4-dimethoxybenzene. This is a Friedel-Crafts Alkylation reaction. LOCH3 (H3C);C, LOCH3 (CH),СОН CH;COOH/H,SO4 H;CO H;CO `C(CH3)3
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can you explain in paragraph, how the current reaction is taking place, and each step.
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- Q12. (1bremeetblbenzene 1 ydergOesan elimination following an E1 mechanism. Fill in the following synthetic scheme by drawing the structure of intermediate 2 and product 3. The chemical formula of product 3 is provided as guidance.Rank the compounds in each group in order of increasing reactivity in electrophilic aromatic substitution: (a) C6H6, C6H5Cl, C6H5CHO, C6H5OCH3; (b) C6H5CH3, C6H5NH2, C6H5CH2NH2, C6H5CONH2.(b) How can be prepared from OEt CO,Et and at EtO OEt EtO2C 95 °C ? Provide the mechanism.
- Provide to llaving Br a detailed, step by step mechanism for the reaction OCH₂CH3₂ OCH₂CH3 OCH₂ CH3Chemistry 3. Complete the following reaction scheme. Give all product(s) and indicate major or minor and any relevant stereochemistry. (а) NaOEt heat (b) heat (c) Br NaCN DMF (d) (e) OH H,SO,/H,PO, heat (f) HBr (g) 1) BH. THE 2) H,0, OH (h) 1) Hg(OAC), H-0 2) NaBH, (i) KMNO, NaOH ColdKeller (c) HOW ОН provide the mechanism: Bonus ICA H₂SO4 НО III.. ...OH
- Peroxides) (a) CH3 CH3 (b) CHCH3 HI HBr CH3CH2Ċ=CHCHCH3Consider the reaction scheme shown below. HCI [1] ОН (a) Provide a detailed mechanism for reaction [1].Give the IUPAC name for each metal salt of a carboxylate anion: (a) CgHsCO, Li"; (b) HCO, Na"; (c) (CH)2CHCO, K*; (d) (CH;CH2)2CHCH;CH(Br)CH2CHCO2 Na*.
- 19). What is the major organic product of the following reactions? LBCH COOH 2. Pyridine ? (-HB) (4) D C " & & & & &OH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO21. Propose a plausible mechanism for the reaction schemes below using curved arrow notation to illustrate electron flow; be sure to show all charges and intermediates. () mechanism a) OH 1 eq. Cl₂ 2 + HCI mechanism b) D2SO4 озв