In the following reactions, identify the Lewis acid and the Lewis base.(a) AlCl3 + Cl¯ → AICI,(b) CH;COOH(aq) + NH3(aq) → CH;COO (aq) + NH (aq)(c) Co³* (aq) + 6F (aq) → [CoF, j*¯ (aq)

A Lewis acid is a chemical species that contains an empty orbital which is capable of accepting an…

Answered: In the following reactions, identify…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter15: Acid–base Equilibria

Section: Chapter Questions

Problem 7P

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For the following acid-base reaction, (1) predict the products, showing both reactants and products complete Lewis structures and arrows showing electron flow; (2) label each structure with the lowing: Bronsted acid, Bronsted base, conjugate acid, conjugate base; (3) give a brief definition of a ronsted acid and Bronsted base; (4) predict the direction of the equilibrium and justify your answer. HC0OH + CH3 Nta PRん106Y pkb = 3.36
Ammonia, NH3, is amphoteric. (a) Give the formula for the conjugate acid of NH3. (b) Give the formula for the conjugate base of NH3.
3 Co(s) + 2 NO 3- (aq) + 8 H+ (aq) = 3 Co 2+ (aq) + 2 NO (g) + 4 H2O (l) What would be the pH of the solution at standard conditions?( HINT: What are the concentrations of all aqueous species at standard conditions?)
(i) Define pH in words. The strong acid HClaq has a pH value of 1, use the following equation for a strong acid: HClaq à H+aq + Cl-aq and convert the following expression to deduce the hydrogen ion concentration: pH = -log10 [H+] (ii) Use the above expression to deduce the pH of HCl (aq) given the concentration of the acid to be 4.5 mol/dm3
(i) Define pH in words. The strong acid HClaq has a pH value of 1, use the following equation for a strong acid: HClaq à H+aq + Cl-aq and convert the following expression to deduce the hydrogen ion concentration: pH = -log10 [H+] (ii) Use the above expression to deduce the pH of HCl (aq) given the concentration of the acid to be 4.5 mol/dm3 pH =
Predict whether aqueous solutions of the following substances are acidic, basic, or neutral and write hydrolysis equations for the acidic and basic solutions. (a) CsBr; (b) Al(NO3)3; (c) KCN; (d) CH3NH3Cl
The ionization constant of lactic acid, CH,CH(OH)CO,H, an acid found in the blood after strenuous exercise, is 1.36 x 10-4. What is the concentration of hydronium ion in the solution of 0.102 M lactic acid? CH;CH(OH)CO,H (aq) + H,O (1) → H;O• (aq) + CH;CH(OH)CO, (aq) O 0.00372 M O 0.0165 M O 0.00549 M O 0.227 M
8. (a) HA(aq) is a weak acid with a dissociation constant, Ka, of 8.8 x 10−12. What is the pH of a 0.022 M solution of A−(aq)? The temperature is 25 ◦C. (b) For the reaction A(g) =A(l), the equilibrium constant is 0.666 at 25.0 ◦C and 0.222 at 75.0 ◦C. Making the approximation that the entropy and enthalpy changes of this reaction do not change with temperature, at what temperature will the equilibrium constant be equal to 0.777?
The pH of an aqueous solution of 0.291 M ammonium perchlorate, NH4C1O4 (aq), is This solution is (Assume that K (NH3) = 1.80 × 10-5.)
Based on the Lewis structures of the reactants and product of the following equation, identify the Lewis acid and the Lewis base in it: CO, + OH → HCO, =c=0: + :0-H H-0- O: O Lewis acid: CO,; Lewis base: HCO, O Lewis acid: OH; Lewis base: CO, O Lewis acid: CO; Lewis base: OH-
3. A 0.0560 g quantity of acetic acid is dissolved in enough water to make 50.0 mL of solution. Calculate the concentrations of H;O*, CH;COO and CH;COOH at equilibrium. What is the pH of the solution? (Ka = 1.8x10) CH;COOH(aq) = CH;COO (aq) + H;O* (aq) a) Calculate the initial concentration of CH;COOH. (C:12; H:1; 0:16) b) Calculate the concentration of CH;CoO (aq) and H;O* (aq) at equilibrium. c) Calculate pH of the solution.
In the following acid-base equilibria of weak acids in water, label the acid (A), the base (B), the conjugate acid (CA), and the conjugate base (CB). HCIO, (aq) + H,O(1) = H,O*(aq) + CI0, (aq) H,CO, (aq) + H,O1) – H;O*(aq) + HCO; (aq) Answer Bank H,O(1) + CH;NH†(aq) = CH,NH,(aq) + H;O*(aq) СА А B СВ CH, COOH(aq) + H,O(1) - CH;COO (aq) + H;O*(aq)

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In the following reactions, identify the Lewis acid and the Lewis base. (a) AlCl3 + Cl¯ → AICI, (b) CH;COOH(aq) + NH3(aq) → CH;COO (aq) + NH (aq) (c) Co³* (aq) + 6F (aq) → [CoF, j*¯ (aq)