Match each item to a choice: breaking of double bond using KMN04 oxidation addition of bromine or chlorine to a double bond halogenation addition to the double bond of B-H from borane loss of HX from an alkyl halide dehydrohalogenation addition of peroxide to a double bond hydroboration formation of cyclopropane from a double bond Simmons-Smith reaction Choices: : hydroxylation # oxymercuration # epoxidation # ozonolysis # dehydration

Match each item to a choice: breaking of double bond using KMN04 oxidation addition of bromine or chlorine to a double bond halogenation addition to the double bond of B-H from borane loss of HX from an alkyl halide dehydrohalogenation addition of peroxide to a double bond hydroboration formation of cyclopropane from a double bond Simmons-Smith reaction Choices: : hydroxylation # oxymercuration # epoxidation # ozonolysis # dehydration

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter10: Alcohols

Section: Chapter Questions

Problem 10.52P: Alcohols are important for organic synthesis, especially in situations involving alkenes. The...

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7:21 PM Thu Jul 7 2req 2req ts 2req pts 2req 1 pts 2req [Review Topics] Provide an IUPAC name for the structure shown. ball & stick-labels (Do not use stereochemical terms in you name.) Submit Answer Retry Entire Group 9 more group attempts remaining [References] 29%
to doinw 4. -> A) Which of the following is NOT a suitable diene for a Diels-Alder reaction? ultiple alkylation B) HBr CHEM 242 Activity 2.1-Conjugated-Systems D) 5. In the addition of HBr to 1,3-butadiene, one product is called the kinetic product and the other is called the thermodynamic product. doccriptors that apply to the kinetic product.
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Part C butan-2-ol butan-2-one, CH3COCH2CH3. NaOCI НОАС EtMgBr H;Ot H2CRO4 ether or PCC excess NaOCI ТЕМРО H,CrO4 1 eq. NaOCI ТЕМРО РСС NaOCI HOAC H2CrO4 or PCC
b) Which of these dienophiles gives the FASTEST reaction with cyclopentadiene? CH2 CH2 A. | В. C. | D. | Give structures for the major Diels-Alder product of the following reactions: 1,3- cyclohexadiene and tetrachloroethene 1,3-cylcohexadiene and fumaric acid, the trans isomer of maleic acid с.
Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.
Compound C is? Compound C-DEPT 135 90 H3C I 70 CH3 CH 4 I 8 (ppm) CI CH₂CH₂CH-Cl CH₂ CH3 CH3-C-CH3 I Cl 1 I 30 10 CH3CH₂CH₂CH₂-Cl
FCompound 10 is a low-boiling liquid (boiling point 58 "C), that reacts with Br, in CCI, to form a 1,1,2,2-tetra bromide The Mass, RÄCÍTICAL SPECTROSCOPY FCompound 10 is a low-boiling liquid (boiling point 58 "C) that reacts with Br. in CCI, to form a 1,1,2,2-tetra bromiide The R, and 'H NMR spectra, along with "C NMR data ve aiven below Flemental Analysis:C. 48 36. H. 4.06; contains halogen. Mass Spectrum 39 74 50 60 140 150 160 170 180 190 200 30 40 70 80 90 100 110 120 130 mve Infrared Spectrum Wave Number, cm 1 4000 1000 2500 2000 1500 1300 1200 15D0 0 10c0 900 B00 700 15 12 13 14 15 Wavelength, microns " Η NMR ppm. 5 Structurei "C Spectral Data: doublet, 80.4 ppm singlet, 68.3 ppm triplet, 347 ppin 50.0m ude 02000 Brooks/Cole Publishing Company Absorbance
Which is formed in the highest yield from the reaction shown? A) B) CI AIC13 D)
4) Which reagents and conditions should be used for the following reaction? OH O NABH4, CH3OH O CH3COCI, AICI3 O K2Cr207, H2SO4, H2O, heat OPCC, CH2C12 O1) LIAIH4, dry ether; 2) H2O
What diene and dienophile are needed to prepare the following? H
3. Predict the products of the following Diels-Alder reactions. a. NC a. 4. Identify the diene and dienophile used to make these Diel-Alder products. CN CH3 CN CH 3 CO₂CH3 CO₂CH3