Precipitation titration is often used to determine the concentrations of halides. Consider the titration of a 20.00 mL mixture of 0.15 M I- and 0.08 M Cl - with 0.1000 M silver nitrate. The first endpoint is reached when VAg + = 30.00 mL and second endpoint when VAg + = 46.00mL Ksp (AgCl) = 1.82x10-10 , Ksp (AgI) = 8.3x10 -17. Calculate the concentrations of Ag+ when 48.00 mL of Ag+ is added to the solution.  (0.0706 M is not the answer!)

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter7: Neutralization Titrations And Graphical Representations
Section: Chapter Questions
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Precipitation titration is often used to determine the concentrations of halides. Consider the titration of a 20.00 mL mixture of 0.15 M I- and 0.08 M Cl - with 0.1000 M silver nitrate. The first endpoint is reached when VAg + = 30.00 mL and second endpoint when VAg + = 46.00mL Ksp (AgCl) = 1.82x10-10 , Ksp (AgI) = 8.3x10 -17.

Calculate the concentrations of Ag+ when 48.00 mL of Ag+ is added to the solution.  (0.0706 M is not the answer!)

 

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