Provide balanced reactions for the preparation of each compound, with complete Lewis structures for all of the molybdenum complexes. Provide a total valence electron count and delectron count for each complex.  Synthesis of (Et2dtc)2MoO2 :  Ammonium Molybdate Tetrahydrate (NH4)6Mo7O24・4(H2O) Sodium Diethyldithiocarbamate Trihydrate (C2H5)2NCSSNa・ 3(H2O)   Synthesis of (Et2dtc)2MoCl2 (Et2dtc)2MoO2 C10H20MoN2O2S4 HCl   Synthesis of (Et2dtc)2Mo(NNMe2) (Et2dtc)2MoO2 C10H20MoN2O2S4 1,1- Dimethylhydrazine C2H8N2 Synthesis of (Et2dtc)2Mo(NNPH) (Et2dtc)2MoO2 C10H20MoN2O2S4 Sodium Diethyldithiocarbamate Trihydrate (C2H5)2NCSSNa・ 3(H2O) Phenylhydrazine C6H8N2

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 31P
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Provide balanced reactions for the preparation of each compound, with complete Lewis structures for all of the molybdenum complexes. Provide a total valence electron count and delectron count for each complex. 

  1. Synthesis of (Et2dtc)2MoO2 : 

    Ammonium Molybdate

    Tetrahydrate

    (NH4)6Mo7O24・4(H2O)

    Sodium

    Diethyldithiocarbamate Trihydrate

    (C2H5)2NCSSNa・ 3(H2O)

     
  2. Synthesis of (Et2dtc)2MoCl2

    (Et2dtc)2MoO2

    C10H20MoN2O2S4

    HCl

     

  3. Synthesis of (Et2dtc)2Mo(NNMe2)

    (Et2dtc)2MoO2

    C10H20MoN2O2S4

    1,1-

    Dimethylhydrazine

    C2H8N2

  4. Synthesis of (Et2dtc)2Mo(NNPH)

(Et2dtc)2MoO2

C10H20MoN2O2S4

Sodium

Diethyldithiocarbamate Trihydrate

(C2H5)2NCSSNa・ 3(H2O)

Phenylhydrazine C6H8N2

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