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Show how you would accomplish the following synthetic transformations. Show all intermediates.
cyclodecyne ¡ cis@cyclodecene
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- Show the complete conversion for the two reactions below. If more than one step is required, show the major product for each reaction used. For instance, after each reactant you must show the resulting structure. No need to show the mechanism.Synthesis: Synthesize the following compounds using the starting material shown a reagents you may need. Show the product after each step. You do not need to shc and I will assume standard work up unless you indicate otherwise. HO, ÕHConsider the following reaction scheme (note that the reagent shown above the arrow is DBN"). Draw in the expected major product AND indicate what mechanism the reaction will follow. Product: Mechanism:
- Complete the following reactions by providing the missing product(s). Determine what mechanism operates in each case (SN1, Sn2, E1, or E2), Show the stereochemistry of the product(s) where appropriate. If more than one product us formed circle the major one. KCN Br NaOCH2CH3 BrProvide the MAJOR product(s) of each sequence of reactions. Show stereochemistry where applicable and draw out ALL stereoisomers that are performed as MAJOR products. Show ONLY the final product(s) after all steps listed are performed. Assume all reagents are in excess.Using curved-arrow notation, draw out the mechanism for the following reaction. Be sure to include stereochemistry and show all intermediates as well as the final product and include all lone pair electrons. Br Br2, H2O OH
- Show how you would accomplish the following synthetic transformations. Show all intermediates. hex@1@yne ¡ hexanal, CH3(CH2)4CYour task is to convert 2-bromobutane to 1-butene in highest yield. Which reagents would you use? O KOH/H2O O KOH/CH,OH O CH3CH2ONA/CH3CH2OH O CH3ONA/CH3OH O (CH3)3COK/(CH3)3COHProvide a detailed step-wise mechanism for the following reaction. Be sure to show all steps, intermediates, formal changes, and show the movement of electrons with curved arrows. You do not need to show transition states.
- Complete the following reactions by providing the missing product(s). Determine what mechanism operates in each case (SN1, SN2, E1, or E2). Show the stereochemistry of the product(s) where appropriate. If more than one product is formed circle the major one.synthesize the following compound given the starting material. Show all the steps, reagents and mechanisms. Do not skip anything. TAKE INTO ACCOUNT THE SHOWN STEREOCHEMISTRYList all alkene products for each reaction. Write a mechanism for the formation of each product following E1 or E2 mechanisms as appropriate. Be sure to draw arrows for the mechanism.