Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: A COOH D COOH The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. NO₂ Mel, AlCl3 (CH3)2CHCI, AICI 3 B KMnO4, NaOH, heat (followed by H3O* workup) E HNO3, H₂SO4 F HCI, Zn Fuming H₂SO4

Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: A COOH D COOH The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. NO₂ Mel, AlCl3 (CH3)2CHCI, AICI 3 B KMnO4, NaOH, heat (followed by H3O* workup) E HNO3, H₂SO4 F HCI, Zn Fuming H₂SO4

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.56P: Write the products of the following sequences of reactions. Refer to your reaction roadmaps to see...

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Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: COOH NO₂ COOH The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A Mel, AlCl3 B KMnO4, NaOH, heat (followed by H3O+ workup) C HCI, Zn D E F (CH3)2CHCI, AICI 3 HNO3, H2SO4 Fuming H2SO4
IF esize this compound by the → t-butyl ethyl ether Show the steps necessary to synthesize this compound by a rignard reaction. Start with an alkyl halide; after that you can add any organic or inorganic compound. → 1-hexanol Consider the following compounds:
Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A OEt 1) EtMgBr 2) H₂O* D NaOEt, heat B HNO3, H₂SO4 E NaOH, heat с F Cl₂, AICI3 CH3CH₂COCI, AICI
Write a mechanism that accounts for the formation of ethyl isopropyl ether as one of the products in the following reaction. CI OEt HCI EtOH Write the mechanism for step one of this reaction. Show lone pairs and formal charges. Only the acidic hydrogen should be drawn out with a covalent bond. Write the mechanism for step two of this reaction (where the product of step one reacts with the solvent, ethanol). Show lone pairs and formal charges. Only the acidic hydrogen should be drawn out with a covalent bond. Write the mechanism for the last step of this reaction (formation of ethyl isopropyl ether). Show lone pairs and formal charges. Only the acidic hydrogen should be drawn out with a covalent bond. CI will act as the base in this reaction.
Starting with benzene and using any other reagents of your choice, design a synthesis for the following compound: CI * Incorrect. COOH A Br The target molecule above can be prepared by treating benzene with some reagent or combination of the reagents listed below. Give the necessary reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. ECABF D NO₂ 1) KMnO4, NaOH, heat 2) H3O+ HNO3, H₂SO4 B E 1) CO2 2) H3O+ (CH3)2CHCI, AICI 3 с Br2, AlBr3 F Cl2, AICI 3
. Please provide a forward synthesis for the following aromatic compounds using benzene as the starting material for all of your syntheses. In some cases, you might run a reaction that produces two products. This outcome is fine; just draw both products, and indicate that you will separate them, and then proceed forward with the compound needed. Br HO2C, Br CI
Provide reagents/conditions to accomplish the following syntheses. Several steps are required in some cases. H2N NH2 Но TH. NH2 HO
Following is the structural formula of the tranquilizer meparfynol (Oblivon). Propose a synthesis for this compound starting with acetylene and a ketone. (Notice the -yn- and -ol in the chemical name of this compound, indicating that it contains alkyne and hydroxyl functional groups.)
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All rearrangements we have discussed so far have involved generation of an electron-deficient carbon followed by a 1,2-shift of an atom or a group of atoms from an adjacent atom to the electron-deficient carbon. Rearrangements by a 1,2-shift can also occur following the generation of an electron-deficient oxygen. Propose a mechanism for the acid-catalyzed rearrangement of cumene hydroperoxide to phenol and acetone.
Write the products of the following sequences of reactions. Refer to your reaction roadmaps to see how the combined reactions allow you to navigate between the different functional groups. Note that you will need your old Chapters 611, Chapters 1518, and Chapter 19 roadmaps along with your new Chapter 20 reaction roadmap for these.
Using your reaction roadmaps as a guide, show how to convert propane into propyl propanoate. You must use propane as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.