Suppose you added 40 mL of water to your vinegar sample instead of 20 mL. Would the titration have required more, less or the same amount of NaOH(aq) for a complete reaction? Explain.
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Suppose you added 40 mL of water to your vinegar sample instead of 20 mL. Would the titration have required more, less or the same amount of NaOH(aq) for a complete reaction? Explain.
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- Separate samples of a solution of an unknown soluble ionic compound are treated with KCl, Na2SO4, and NaOH. A precipitate forms only when Na2SO4 is added. Which cations could be present in the unknown soluble ionic compound?Arsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 25.00-mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample.Experiments show that propionic acid (CH3CH2COOH) is a weak acid. Write the chemical equation.
- Citric acid, which can be obtained from lemon juice, has the molecular formula C6H8O7. A 0.250-g sample of citric acid dissolved in 25.0 mL of water requires 37.2 mL of 0.105 M NaOH for complete neutralization. What number of acidic hydrogens per molecule does citric acid have?n general terms, what are the spectator ions in a precipitation reaction? Why are the spectator ions not included in writing the net ionic equation for a precipitation reaction? Does this mean that the spectator ions do not have to be present in the solution?The Behavior of Substances in Water Part 1: a Ammonia, NH3, is a weak electrolyte. It forms ions in solution by reacting with water molecules to form the ammonium ion and hydroxide ion. Write the balanced chemical reaction for this process, including state symbols. b From everyday experience you are probably aware that table sugar (sucrose), C12H22O11, is soluble in water. When sucrose dissolves in water, it doesnt form ions through any reaction with water. It just dissolves without forming ions, so it is a nonelectrolyte. Write the chemical equation for the dissolving of sucrose in water. c Both NH3 and C12H22O11 are soluble molecular compounds, yet they behave differently in aqueous solution. Briefly explain why one is a weak electrolyte and the other is a nonelectrolyte. d Hydrochloric acid, HCl, is a molecular compound that is a strong electrolyte. Write the chemical reaction of HCl with water. e Compare the ammonia reaction with that of hydrochloric acid. Why are both of these substances considered electrolytes? f Explain why HCl is a strong electrolyte and ammonia is a weak electrolyte. g Classify each of the following substances as either ionic or molecular. KCl NH3 CO2 MgBr2 HCl Ca(OH)2 PbS HC2H3O2 h For those compounds above that you classified as ionic, use the solubility rules to determine which are soluble. i The majority of ionic substances are solids at room temperature. Describe what you would observe if you placed a soluble ionic compound and an insoluble ionic compound in separate beakers of water. j Write the chemical equation(s), including state symbols, for what happens when each soluble ionic compound that you identified above is placed in water. Are these substances reacting with water when they are added to water? k How would you classify the soluble ionic compounds: strong electrolyte, weak electrolyte, or nonelectrolyte? Explain your answer. l Sodium chloride, NaCl, is a strong electrolyte, as is hydroiodic acid, HI. Write the chemical equations for what happens when these substances are added to water. m Are NaCl and HI strong electrolytes because they have similar behavior in aqueous solution? If not, describe, using words and equations, the different chemical process that takes place in each case. Part 2: You have two hypothetical molecular compounds, AX and AY. AX is a strong electrolyte and AY is a weak electrolyte. The compounds undergo the following chemical reactions when added to water. AX(aq)+H2O(l)AH2O+(aq)+X(aq)AY(aq)+H2O(l)AH2O+(aq)+Y(aq) a Explain how the relative amounts of AX(aq) and AY(aq) would compare if you had a beaker of water with AX and a beaker of water with AY. b How would the relative amounts of X(aq) and Y(aq) in the two beakers compare? Be sure to explain your answer.
- One method for determining the purity of aspirin (C9H8O4) is to hydrolyze it with NaOH solution and then to titrate the remaining NaOH. The reaction of aspirin with NaOH is as follows: A sample of aspirin with a mass of 1.427 g was boiled in 50.00 mL of 0.500 M NaOH. After the solution was cooled, it took 31.92 mL of 0.289 M HCl to titrate the excess NaOH. Calculate the purity of the aspirin. What indicator should be used for this titration? Why?Write a balanced equation for the reaction of hydroiodic acid, HI, with calcium hydroxide, Ca(OH)2. Then, write the balanced complete ionic equation and the net ionic equation for this neutralization reaction.A student mixes four reagents together, thinking that the solutions will neutralize each other. The solutions mixed together are 50.0 mL of 0.100M hydrochloric acid, 100.0 mL of 0.200 M of nitric acid, 500.0 mL of 0.0100 M calcium hydroxide, and 200.0 mL of 0.100 M rubidium hydroxide. Did the acids and bases exactly neutralize each other? If not, calculate the concentration of excess H+ or OH ions left in solution.
- Consider the following generic equation: H+(aq)+ B(aq)HB(aq)For which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) nitric acid and calcium hydroxide (b) hydrochloric acid and CH3NH2 (c) hydrobromic acid and aqueous ammonia (d) perchloric acid and barium hydroxide (e) sodium hydroxide and nitrous acidDescribe some physical and chemical properties of acids and bases. What is meant by a strong acid or base? Are strong acids and bases also strong electrolytes? Give several examples of strong acids and strong bases.Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?
