Answered: Suppose you have 1.00 moles of the acid…

Suppose you have 1.00 moles of the acid NH4* and want to prepare a buffer with [NH3]/[NH4*] = 1.50. How many moles of NaOH must be added? moles

General, Organic, and Biological Chemistry

7th Edition

ISBN:9781285853918

Author:H. Stephen Stoker

Publisher:H. Stephen Stoker

Chapter10: Acids, Bases, And Salts

Section: Chapter Questions

Problem 10.118EP: Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer...

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Suppose you have 1.00 moles of the acid NH4 and want to prepare a buffer with [NH3]/[NH4] = 1.50. How many moles
of NaOH must be added?
moles
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Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
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8-55 We commonly refer to a buffer as consisting of approximately equal molar amounts of a weak acid and its conjugate base—for example, CH3COOH and CH3COO-. Is it also possible to have a buffer consisting of approximately equal molar amounts of a weak base and its conjugate acid? Explain.
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Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.
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