The resistance of 0.01M acetic acid solution is found to be 222002, when measured in a cellhas two electrodes of area of cross section 3.85cm² placed 10.5cm apart. Calculateconductivity.
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- Far the cell: pt/ Hz clatuy / NaOH Com)/ Hg0 cs)/ Hg cel -0.924V 854V 198K eatcutate standard eledromotive force Eas K write the eleetreds reaehions and the ett reaction So calculate the electromotive force at s08 K the change in inthalpy (AH)= and, what happen to electramotive forcewihen adokd few amount of nitrie acid to equitalent to the base Hg/Hg when - 35 kcal to cell reachin NaoH partially 2116.In a conductivity cell of a cell constant 0.003 cm³¹ concentration of 0.01 M solution of acetic acid, the resistance against ionic mobility is 20 ohm at 25 °C. the degree of dissociation of the acid is (where the molar conductance at infinite dilution = 390 x 104 2¹¹ m² mol¹ at 25° C) a) 0.015 b) 0.027 c) 0.038 d) 0.047A conductivity cell filled with a 0.01 M KCl solution was found to have a resistance of 189 ohms at 25oC. When filled with 0.01 M HCl solution, the cell gave a resistance of 64.8 ohms at the same temperature. At 25oC, the conductivity of 0.01 M KCl solution was 1.4088 x 10-3 S cm-1. Calculate (a) the cell constant and (b) the conductivity of the HCl solution. answer is [0.266; 4.105 x 10-3] please explain. thank you!
- 1. A Cr3+ solution is electrolyzed using a current of0.365 A. What mass of Cr(s) (51.9661) is plated outafter 10 hours?2. When an aqueous solution of CuSO4 is electrolyzedcopper metal is deposited. If a constant current waspassed for 5.00 h and 404 mg of Cu (63.546) metal wasdeposited, what was the current?4. The %Mn in steel can also be determined spectrophotometrically by oxidizing the manganese to the intensely colored permanganate, MnO4-. Standard solutions of permanganate gave the following absorbances (in a 1 cm cell): ABSORBANCE CONC. OF MnO4 (g/mL) 0.210 1.05 x 10-5 0.315 1.61 x 10-5 0.429 2.21 x 10-5 0.599 2.98 x 10-5 0.801 4.04 x 10-5 The following samples of steel were thoroughly reacted to convert the manganese into permanganate and then diluted to 500.00 mL. WT. OF STEEL (g) ABSORBANCE 0.5886 0.611 0.3498 0.359 0.4555 0.482 Again using Excel, plot the calibration data and calculate the %Mn in the steel.= 8. The following is a Frost diagram of phosphorus in aqueous solution at pH 0. Specify the form of P that is: (i) the most thermodynamically stable; (ii) the least thermodynamically stable; (iii) unstable and will disproportionate, also specify the new forms that will be made. ZE°/V 0.5 0.0 -0.5 -1.0 -1.5 -2.0 PH3 H3PO₂ -2.5 -3 -2 -1 0 1 2 3 H3PO3 H3PO4 4 5 Oxidation state, N
- Determine the transport numbers of the ions in an exactly 0.200 molal solution of copper (II) sulfate. The cell was filled with solution and electrolyzed between copper electrodes for some time. The cathode solution of the cell was found to weigh 36.434 g and contains 0.4415 g of Cu. Further the cathode in the coulometer showed an increase in weight of 0.0405 g due to deposited Ag.2) A 90.00 ml solution, density = 1.0582 g/mL. with a AG = specif ic heat of 4.079 J/(GC), increased in temperature ΔΗ- from 20.36 C to 28.13 t with Al added. The copper collected, weighed 2.087 g. The electrochemical AS = potential mean was +1.821 volts. Calculate AG AH and AS for the reaction below. +3 2A (aq) +2 2 Als) * 3 Cuaq) 3 C46)(8) The cell: SCE//HA(0.250M), NaA(0.170M)/H2(1.00bar), Pt has a poten- tial of -0.721V at 298K. (The SCE electrode potential is +0.2444V) (a) Sketch this cell. (b) What is potential of this cell vs. Ag/AgCl/sat'd KCI? (c) Calculate the dissociation constant of HA neglecting the junction poten- tial.
- (Please give clear handwritten answer) 0.1 M HNO3 solution at 298K was electrolyzed in Hittorf cell using platinum electrodes. After electrolysis, 34.2 mg of copper was deposited in coulometer which in series with the Hittorf cell. 50 mL of HNO3 solution was withdrawn from anode compartment after electrolysis and found to have a concentration of 0.0821 M. [Atomic mass Cu = 63]. (i) Find the transference number of H + and NO3 −. (ii) If 50 mL HNO3 solution was run off from cathode compartment, what would its concentration be?A (0.002M) Cu2+ solution gave an absorbance of 0.50 at 560 nm in a 1.0 cm cell. The molar absobitivity of solution is equel:(d) Calculate the electrical conductivity of a 6.0 mm diameter cylindrical silicon specimen of 60 mm long in which a current of 0.5 A passes in an axial direction. A voltage of 12.5 V is measured across two probes that are separated by 40 mm. i. Compute the electrical conductivity of the specimen. C12334 ii. Compute the resistance over the entire 60 mm of the specimen using the data in (1).