24 The standard reaction free energyN2(g) + 3H2(g) →2 NH3(9)AGO==-34. kJ for this reaction:Use this information to complete the table below. Round each of your answers to the nearest kJ.reaction1413NH₁ (g) → ½ ½№2 (g) + H2(g)N₂3№2(g) + H₁₂ (g) → ½ ½ NH₁ (g)4→>>2NH, (g) N2(g) + 3H2(g)AGº0☐ x10☐ kJ☑☐ kJ☐ kJ

Answered: Image /qna-images/answer/f2d2cfd4-2cc4-4597-a293-ae6f850681b7.jpg

Answered: The standard reaction free energy N2(g)…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter5: Thermochemistry

Section: Chapter Questions

Problem 5.46QE

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Insoluble PbBr2(s) precipitates when solutions of Pb(NO3)2(aq) and NaBr(aq) are mixed. Pb(NO3)2(aq) + 2 NaBr(aq) PbBr2(s) + 2 NaNO3(aq) rH = ? To measure the enthalpy change, 200. mL. of 0.75 M Pb(NO3)2(aq) and 200. mL of 1.5 M NaBr(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises by 2.44 C. Calculate the enthalpy change for the precipitation of PbBr2(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL., and its specific heat capacity is 4.2 J/g K.)
9.96 Most first aid "cold packs" are based on the endothermic dissolution of ammonium nitrate in water: NH4NO3(s)NH4+(aq)+NO3(aq) H= 25.69 kJ A particular cold pack contains 50.0 g of NH4NO3 and 125.0 g of water. When the pack is squeezed, the NH4NO3dissolves in the water. If the pack and its contents are initially at 24.0°C, what is the lowest temperature that this bag could reach? (Assume that the ammonium nitrate solution has a specific heat of 4.25J g-l K-l, and that the heat capacity of the bag itself is small enough to be neglected.)
A 50-mL solution of a dilute AgNO3 solution is added to 100 mL of a base solution in a coffee-cup calorimeter. As Ag2O(s) precipitates, the temperature of the solution increases from 23.78 C to 25.19 C. Assuming that the mixture has the same specific heat as water and a mass of 150 g, calculate the heat q. Is the precipitation reaction exothermic or endothermic?
The enthalpy changes of the following reactions can be measured: C2H4(g) + 3 O2(g) 2 CO2(g) + 2 H2O() rH = 1411.1 kJ/mol-rxn Q2H5OH() + 3 O2(g) 2 CO2(g) + 3 H2O() rH = 1367.5 kJ/mol-rxn (a) Use these values and Hesss law to determine the enthalpy change for the reaction C2H4(g) + H2O() C2H5OH() (b) Draw an energy level diagram that shows the relationship between the energy quantities involved in this problem.
A piece of lead of mass 121.6 g was heated by an electrical coil. From the resistance of the coil, the current, and the Time the current flowed, it was calculated that 235 J of heat was added to the lead. The temperature of the lead rose from 20.4C to 35.5C. What is the specific heat of the lead?
A 21.3-mL sample of 0.977 M NaOH is mixed with 29.5 mL of 0.918 M HCl in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 19.6C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, the specific heat of all solutions is the same as that of water, and volumes are additive.
A 29.1-mL sample of 1.05 M KOH is mixed with 20.9 mL of 1.07 M HBr in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 21.8C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, and volumes are additive.
The enthalpy changes for the following reactions can be measured: CH4(g) + 2 O2(g) CO2(g) + 2 H2O(g) rH = 802.4 kJ/mol-rxn CH3OH(g) + 32 O2(g) CO2(g) + 2 H2O(g) rH = 676 kJ/mol-rxn (a) Use these values and Hesss law to determine the enthalpy change for the reaction CH4(g) + O2(g) CH3OH(g) (b) Draw an energy level diagram that shows the relationship between the energy quantities involved in this problem.
Alloys When a 58.8-g piece of hot alloy is placed in125 g of cold water in a calorimeter, the temperature ofthe alloy decreases by 106.1°C, while the temperature ofthe water increases by 10.5°C. What is the specific heat ofthe alloy?
Shown below is a diagram depicting the enthalpy change of a chemical reaction run at constant pressure. a Is the reaction exothermic or endothermic? b What is the sign of H? c What is the sign of q? d If the reaction does no work, what is the sign of E for this process?

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