This energy diagram shows the allowed energy levels of an electron in a certain atom -D energy C Which is the ground state? B A Use this diagram to complete the table below. How many excited states are there? How many lines are in the absorption line spectrum? Which transition causes the emission line at the shortest wavelength? Which transition causes the emission line at the longest wavelength? (pick one) 0 0 0 →0 0-0

This energy diagram shows the allowed energy levels of an electron in a certain atom -D energy C Which is the ground state? B A Use this diagram to complete the table below. How many excited states are there? How many lines are in the absorption line spectrum? Which transition causes the emission line at the shortest wavelength? Which transition causes the emission line at the longest wavelength? (pick one) 0 0 0 →0 0-0

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter5: Electron Configurations And The Periodic Table

Section: Chapter Questions

Problem 31QRT

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6.12 Find the energy of a photon with each of the following frequencies (see Table 1.2 if needed). (a) 15.3 THz, (b) 1.7 EHz, (c) 6.221010 Hz
6.93 A mercury atom is initially in its lowest possible (or ground state) energy level. The atom absorbs a photon with a wavelength of 185 nm and then emits a photon with a frequency of 4.9241014HZ . At the end of this series of transitions, the atom will still be in an energy level above the ground state. Draw an energy-level diagram for this process and find the energy of this resulting excited state, assuming that we assign a value of E = 0 to the ground state. (This choice of E = 0 is not the usual convention, but it will simplify the calculations you need to do here.)
Investigating Energy Levels Consider the hypothetical atom X that has one electron like the H atom but has different energy levels. The energies of an electron in an X atom are described by the equation E=RHn3 where RH is the same as for hydrogen (2.179 1018 J). Answer the following questions, without calculating energy values. a How would the ground-state energy levels of X and H compare? b Would the energy of an electron in the n = 2 level of H be higher or lower than that of an electron in the n = 2 level of X? Explain your answer. c How do the spacings of the energy levels of X and H compare? d Which would involve the emission of a higher frequency of light, the transition of an electron in an H atom from the n = 5 to the n = 3 level or a similar transition in an X atom? e Which atom, X or H, would require more energy to completely remove its electron? f A photon corresponding to a particular frequency of blue light produces a transition from the n = 2 to the n = 5 level of a hydrogen atom. Could this photon produce the same transition (n = 12 to n = 5) in an atom of X? Explain.
A photon with a wavelength of 93.8 nm strikes a hydrogen atom, and light is emitted by the atom. How many emission lines would be observed? At what wavelengths? Explain briefly (see Figure 6.10).
Human color vision is " produced" by the nervous system based on how three different cone receptors interact with photons of light in the eye. These three different types of cones interact with photons of different frequency light, as indicated in the following chart: Cone Type Range of Light Frequency Detected S 6.00-7.49 1014s1 M 4.76-6.62 1014s1 L 4.28-6.00 1014s1 What wavelength ranges (and corresponding colors) do the three types of cones detect?
Consider the bright line spectrum of hydrogen shown in Fig. 11.10 . Which line in the spectrum represents photons with the highest energy? With the lowest energy?
What is the difference between an atom’s ground state and an excited state?
As the weapons officer aboard the Srarship Chemistry, it is your duty to configure a photon torpedo to remove an electron from the outer hull of an enemy vessel. You know that the work function (the binding energy of the electron) of the hull of the enemy ship is 7.52 1019 J. a. What wavelength does your photon torpedo need to be to eject an electron? b. You find an extra photon torpedo with a wavelength of 259 nm and fire it at the enemy vessel. Does this photon torpedo do any damage to the ship (does it eject an electron)? c. If the hull of the enemy vessel is made of the element with an electron configura tion of [Ar]4s13d10, what metal is this?

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